Synthesis and X-ray Characterization of Alkali Metal 2-Acyl-1, 1, 3, 3-tetracyanopropenides
SV Karpov, AA Grigor'ev, YS Kayukov… - The Journal of …, 2016 - ACS Publications
A novel route for synthesis of 2-acyl-1, 1, 3, 3-tetracyanopropenides (ATCN) salts in high
yields and excellent purities starting from readily available methyl ketones, malononitrile …
yields and excellent purities starting from readily available methyl ketones, malononitrile …
1, 1′-Diethyl-4, 4′-bipyridine-1, 1′-diium bis (1, 1, 3, 3-tetracyano-2-ethoxypropenide): multiple C—H⋯ N hydrogen bonds form a complex sheet structure
In the title salt, C14H18N22+· 2C9H5N4O−, the 1, 1′-diethyl-4, 4′-bipyridine-1, 1′-diium
dication lies across a centre of inversion in the space group P21/c. In the 1, 1, 3, 3 …
dication lies across a centre of inversion in the space group P21/c. In the 1, 1, 3, 3 …
The synthesis, characterization, X-ray structure and magnetism of dinuclear-based bis [μ-(1, 1, 3, 3-tetracyano-2-ethoxypropenido-κ2N, N′)(1, 1, 3, 3-tetracyano-2 …
Abstract The monoanionic ligand 1, 1, 3, 3-tetracyano-2-ethoxypropenide (tcnoet) is
reported with its Cu II–bpy complex of formula [Cu 2 (μ-tcnoet) 2 (tcnoet) 2 (bpy) 2]. The …
reported with its Cu II–bpy complex of formula [Cu 2 (μ-tcnoet) 2 (tcnoet) 2 (bpy) 2]. The …
Synthesis of novel polycyano-containing organic ligands via double carbanion cleavage of 1′, 3′-dioxo-1′, 3′-dihydrospiro [cyclopropane-1, 2′-indene] …
SV Karpov, YS Kaukov, AA Grigor'ev… - Organic & …, 2016 - pubs.rsc.org
A novel fast, convenient and inexpensive synthesis of 1′, 3′-dioxo-1′, 3′-dihydrospiro
[cyclopropane-1, 2′-indene]-2, 2, 3, 3-tetracarbonitrile and dimethyl 2, 3-dicyano-1′, 3 …
[cyclopropane-1, 2′-indene]-2, 2, 3, 3-tetracarbonitrile and dimethyl 2, 3-dicyano-1′, 3 …
The first Fe (II) complex bearing end-to-end dicyanamide as a double bridging ligand: Crystallography study and Hirshfeld surface analysis; completed with a CSD …
Two new polymeric, one and two-dimensional compounds [Fe (dmbpy)(μ 1, 5-dca) 2](1) and
[Fe (4, 4′-bpy)(μ 1, 5-dca) 2]. 0.24 (4, 4′-bpy). 0.5 (EtOH)(2), in which dmbpy= 5, 5 …
[Fe (4, 4′-bpy)(μ 1, 5-dca) 2]. 0.24 (4, 4′-bpy). 0.5 (EtOH)(2), in which dmbpy= 5, 5 …
Three zinc (II) and cadmium (II) complexes containing 4-amino-3, 5-bis (pyridin-2-yl)-1, 2, 4-triazole and polynitrile ligands: Synthesis, molecular and supramolecular …
Three photoluminescent complexes containing either ZnII or CdII have been synthesized
and their structures determined. Bis [4-amino-3, 5-bis (pyridin-2-yl)-1, 2, 4-triazole-κ2N1, N5] …
and their structures determined. Bis [4-amino-3, 5-bis (pyridin-2-yl)-1, 2, 4-triazole-κ2N1, N5] …
Tris (2, 2′-bipyridine) iron (II) bis (1, 1, 3, 3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions
In the title compound,[Fe (C10H8N2) 3](C9H5N4O) 2· 2H2O, the chiral cations lie across
twofold rotation axes in the space group C2/c. The anions and the water molecules are …
twofold rotation axes in the space group C2/c. The anions and the water molecules are …
[HTML][HTML] The non-coordinating anion 1, 1, 3, 3-tetracyano-2-propoxy-propenide as an anion-π donor in cis-diaquabis (2, 2′-dipyridylamine) zinc and its cadmium …
The synthesis, structure and properties of cis-diaquabis (2, 2′-dipyridylamine) zinc bis (1, 1,
3, 3-tetracyano-2-propoxy-propenide),[Zn (H 2 O) 2 (2, 2′-dpa) 2][tcnopr] 2, I, and its …
3, 3-tetracyano-2-propoxy-propenide),[Zn (H 2 O) 2 (2, 2′-dpa) 2][tcnopr] 2, I, and its …
[HTML][HTML] Synthesis, structure and luminescence properties of zinc and cadmium linear-chain compounds with anionic monoalkoxy-tetracyanopropenes bridged by 4, 4 …
The synthesis, characterization and 3D structure determination of Zinc and Cadmium
compounds are reported, containing the non-chelating bidentate ligand 4, 4′-bipyridine …
compounds are reported, containing the non-chelating bidentate ligand 4, 4′-bipyridine …
2-Acyl-1, 1, 3, 3-tetracyanopropenides (ATCN): structure characterization and luminescence properties of ammonia and alkali metal ATCN salts
YS Kayukov, SV Karpov, AA Grigor'Ev… - Dalton …, 2017 - pubs.rsc.org
Herein, syntheses, crystal structures, and photoluminescence properties of 24 new ammonia
and alkali metal ATCN salts characterized via single-crystal X-ray diffraction are reported …
and alkali metal ATCN salts characterized via single-crystal X-ray diffraction are reported …