Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands

J Takaya - Chemical Science, 2021 - pubs.rsc.org
Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …

Coordination-and redox-noninnocent behavior of ambiphilic ligands containing antimony

JS Jones, FP Gabbai - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Stimulated by applications in catalysis, the chemistry of ambiphilic ligands
featuring both donor and acceptor functionalities has experienced substantial growth in the …

[图书][B] Ligand Design in Metal Chemistry

M Stradiotto, RJ Lundgren - 2016 - Wiley Online Library
Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

Activation of a hydroamination gold catalyst by oxidation of a redox-noninnocent chlorostibine Z-ligand

H Yang, FP Gabbaı̈ - Journal of the American Chemical Society, 2015 - ACS Publications
In search of new platforms that support redox-controlled catalysis, we have investigated the
noninnocent behavior of chlorostibine ligands coordinated to gold. The gold chlorostibine …

Stibonium Ions for the Fluorescence Turn-On Sensing of F in Drinking Water at Parts per Million Concentrations

IS Ke, M Myahkostupov, FN Castellano… - Journal of the …, 2012 - ACS Publications
The 9-anthryltriphenylstibonium cation,[1]+, has been synthesized and used as a sensor for
the toxic fluoride anion in water. This stibonium cation complexes fluoride ions to afford the …

Tunable σ-accepting, Z-type ligands for organometallic catalysis

D You, FP Gabbaï - Trends in Chemistry, 2019 - cell.com
Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …

[图书][B] Frustrated Lewis Pairs

G Erker, DW Stephan - 2013 - Springer
Up until recently, our understanding of the chemistry resulting from the combination of Lewis
acids and bases had not evolved much since Lewis' time. In large part, the formation of …

Molecular Bismuth Cations: Assessment of Soft Lewis Acidity

J Ramler, C Lichtenberg - Chemistry–A European Journal, 2020 - Wiley Online Library
Three‐coordinate cationic bismuth compounds [Bi (diaryl)(EPMe3)][SbF6] have been
isolated and fully characterized (diaryl=[(C6H4) 2C2H2] 2−, E= S, Se). They represent rare …

Intermolecular Metal-Involving Pnictogen Bonding: The Case of σ-(SbIII)-Hole···dz2[PtII] Interaction

AM Cheranyova, LE Zelenkov, SV Baykov… - Inorganic …, 2024 - ACS Publications
Cocrystallizations of trans-[PtX'2 (NCNR2) 2](R2= Me2, X'= Cl 1a, Br 1b, I 1c; R2=(CH2) 5,
X'= I 2c) with SbX3 (X= Cl, Br, I) gave 1: 2 cocrystals 1a· 2SbCl3, 1b· 2SbBr3, 1c· 2SbCl3, 1c …

Neutral and Cationic Bismuth Compounds: Structure, Heteroaromaticity, and Lewis Acidity of Bismepines

J Ramler, K Hofmann, C Lichtenberg - Inorganic Chemistry, 2019 - ACS Publications
Bismepines are 3-fold unsaturated seven-membered rings containing one bismuth atom. A
set of dibenzobismepine complexes have been synthesized and isolated, among them a …