Ionic liquids: new forms of active pharmaceutical ingredients with unique, tunable properties

JL Shamshina, RD Rogers - Chemical Reviews, 2023 - ACS Publications
This Review aims to summarize advances over the last 15 years in the development of
active pharmaceutical ingredient ionic liquids (API-ILs), which make up a prospective game …

Today's progress in the synthesis of porous carbons from biomass and their application for organic electrolyte and ionic liquid based supercapacitors

PM Yeletsky, MV Lebedeva, VA Yakovlev - Journal of Energy Storage, 2022 - Elsevier
Supercapacitors (SCs) currently attract great attention from researchers working in the field
of energy storage over the world. This review article is focused on the recent advances in the …

Evolution of microscopic heterogeneity and dynamics in choline chloride-based deep eutectic solvents

S Spittle, D Poe, B Doherty, C Kolodziej… - Nature …, 2022 - nature.com
Deep eutectic solvents (DESs) are an emerging class of non-aqueous solvents that are
potentially scalable, easy to prepare and functionalize for many applications ranging from …

Giant and bidirectionally tunable thermopower in nonaqueous ionogels enabled by selective ion doping

S Liu, Y Yang, H Huang, J Zheng, G Liu, TH To… - Science …, 2022 - science.org
Ionic thermoelectrics show great potential in thermal sensing owing to their ultrahigh
thermopower, low cost, and ease in production. However, the lack of effective n-type ionic …

Ionicity of deep eutectic solvents by Walden plot and pulsed field gradient nuclear magnetic resonance (PFG-NMR)

Y Wang, W Chen, Q Zhao, G Jin, Z Xue… - Physical Chemistry …, 2020 - pubs.rsc.org
Deep eutectic solvents (DESs) have attracted considerable attention due to their unique
properties. Owing to similar structures and properties, DESs are also called “quasi-ionic …

Anion intercalation into graphite drives surface wetting

AA Papaderakis, A Ejigu, J Yang… - Journal of the …, 2023 - ACS Publications
The unique layered structure of graphite with its tunable interlayer distance establishes
almost ideal conditions for the accommodation of ions into its structure. The smooth and …

Key factor governing the physicochemical properties and extent of proton transfer in protic ionic liquids: Δp K a or chemical structure?

MS Miran, M Hoque, T Yasuda, S Tsuzuki… - Physical Chemistry …, 2019 - pubs.rsc.org
In order to identify the key factor governing the transport properties and extent of proton
transfer in protic ionic liquids (PILs), a series of PILs were prepared by simple neutralisation …

Thermoelectric ratchet effect for charge carriers with hopping dynamics

A Würger - Physical review letters, 2021 - APS
We show that the huge Seebeck coefficients observed recently for ionic conductors arise
from a ratchet effect where activated jumps between neighbor sites are rectified by a …

Thermopower of ionic conductors and ionic capacitors

A Würger - Physical Review Research, 2020 - APS
We theoretically study the thermoelectric response of ionic conductors to an applied
temperature gradient. As a main result, we find that open and closed systems with respect to …

Broadband NMR relaxometry as a powerful technique to study molecular dynamics of ionic liquids

CC Fraenza, SG Greenbaum - ChemPhysChem, 2023 - Wiley Online Library
Fast field cycling nuclear magnetic resonance (FFC NMR) relaxometry technique has been
demonstrated to be a useful analytical tool to investigate molecular dynamics in very diverse …