N-Heterocyclic carbene complexes in C–H activation reactions
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …
Cross‐Coupling of Heteroarenes by C H Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes …
In recent years, transition metal‐catalyzed direct (hetero) arylation reactions of heteroarenes
with (hetero) aryl halides and pseudohalides have received significant attention as eco …
with (hetero) aryl halides and pseudohalides have received significant attention as eco …
Rhodium-catalyzed atroposelective C–H arylation: efficient synthesis of axially chiral heterobiaryls
Rhodium (I)-catalyzed atroposelective C–H arylation of heterobiaryls was presented. In the
presence of a Rh catalyst derived from [Rh (C2H4) 2Cl] 2 and a TADDOL-derived …
presence of a Rh catalyst derived from [Rh (C2H4) 2Cl] 2 and a TADDOL-derived …
Intramolecular oxidative C− N bond formation for the synthesis of carbazoles: comparison of reactivity between the copper-catalyzed and metal-free conditions
New synthetic procedures for intramolecular oxidative C− N bond formation have been
developed for the preparation of carbazoles starting from N-substituted amidobiphenyls …
developed for the preparation of carbazoles starting from N-substituted amidobiphenyls …
Rhodium-catalyzed intermolecular amidation of arenes with sulfonyl azides via chelation-assisted C–H bond activation
We report the direct amidation of arene C–H bonds using sulfonyl azides as the amino
source to release N2 as the single byproduct. The reaction is catalyzed by a cationic …
source to release N2 as the single byproduct. The reaction is catalyzed by a cationic …
PIII‐Chelation‐Assisted Indole C7‐Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis
X Qiu, P Wang, D Wang, M Wang… - Angewandte Chemie …, 2019 - Wiley Online Library
Rhodium‐catalyzed C7‐selective decarbonylative arylation, olefination, and methylation of
indoles with carboxylic acids or anhydrides by C− H and C− C bond activation have been …
indoles with carboxylic acids or anhydrides by C− H and C− C bond activation have been …
Oxazolinyl-assisted C–H amidation by cobalt (III) catalysis
Cobalt-catalyzed C–H activation by means of oxazolinyl assistance set the stage for
versatile direct amidations with ample substrate scope. Thus, a high-valent cobalt (III) …
versatile direct amidations with ample substrate scope. Thus, a high-valent cobalt (III) …
Ruthenium-catalyzed direct C–H bond arylations of heteroarenes
L Ackermann, AV Lygin - Organic Letters, 2011 - ACS Publications
Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes Page 1 10.1021/ol2010648 r
2011 American Chemical Society Published on Web 06/06/2011 ORGANIC LETTERS 2011 Vol …
2011 American Chemical Society Published on Web 06/06/2011 ORGANIC LETTERS 2011 Vol …
Rhodium-catalyzed C–H bond functionalization with amides by double C–H/C–N bond activation
G Meng, M Szostak - Organic letters, 2016 - ACS Publications
The first C–H bond functionalization with amides as the coupling partners via selective
activation of the amide N–C bond using rhodium (I) catalysts under highly chemoselective …
activation of the amide N–C bond using rhodium (I) catalysts under highly chemoselective …
Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond …
CC Tsai, WC Shih, CH Fang, CY Li… - Journal of the …, 2010 - ACS Publications
We have presented new amino-NHC Ni− Al complex mediated para C− H bond activation
for pyridine and quinolin, and isolated for the first time the intermediate structure of a …
for pyridine and quinolin, and isolated for the first time the intermediate structure of a …