Complexes of the form [(t BuCO2) 3M2] 2 (μ-O2C− X− CO2), where M is Mo or W and X is a
π conjugated organic group, are ideally suited for studies of electronic coupling between the …

Linking organic conjugated systems with MM quadruple bonds (M= Mo or W) allows for the
study of mixed valence metal and organic centered radicals in their ground and photo …

The possible incorporation of the redox active, small donor acceptor molecule azulene as a
core structure for potential optoelectronic applications has been evaluated. The synthesis …

Azulen-2-ylboronic acid pinacol ester, prepared by iridium-catalyzed C–H borylation of
azulene, efficiently underwent iododeboronation with a stoichiometric amount of copper (I) …

To improve the binding energy of hydrogen, incorporation of internally polarized organic
units into metal–organic frameworks (MOFs) should be a promising strategy. In this study …

Three novel dimolybdenum dimers [Mo2 (DAniF) 3] 2 (μ-OSCC6H4CSO),[Mo2 (DAniF) 3] 2
(μ-O2CC6H4CS2), and [Mo2 (DAniF) 3] 2 (μ-S2CC6H4CS2)(DAniF= N, N′-di (p-anisyl) …

Coordination polymers (CPs) supporting tunable through-framework conduction and
responsive properties are of significant interest for enabling a new generation of active …

Mercapto (–SH) and isocyano (–NC) terminated conducting π-linkers are often employed in
the ever-growing quest for organoelectronic materials. While such systems typically involve …

This review is focused on the emerging chemistry of nonbenzenoid aromatic isocyanides, a
relatively new family of aryl isocyanide molecules. Two types of systems are discussed:(1) …

The key step in accessing the title species (5), the first nonbenzenoid diisocyanobiaryl,
involved an unexpected homocoupling of a 6-bromoazulene derivative. The reversible 2e …