Insights into metal/carbon materials activation of persulfate from a structure–property perspective: performances, tunable reaction pathways and toxicity

H Ge, M Cheng, DL Huang, M Yan, Z Wei… - Chemical Engineering …, 2023 - Elsevier
Metal/carbon materials have exhibited great potential for engineering applications in
environmental remediation as efficient catalysts for persulfate-based advanced oxidation …

[HTML][HTML] Carbon-based single-atom catalysts in advanced oxidation reactions for water remediation: from materials to reaction pathways

J Zhang, X Tang, Y Hong, G Chen, Y Chen… - Eco-Environment & …, 2023 - Elsevier
Single-atom catalysts (SACs) have been widely recognized as state-of-the-art catalysts in
environment remediation because of their exceptional performance, 100% metal atomic …

Assessing the use of probes and quenchers for understanding the reactive species in advanced oxidation processes

Y Lei, Y Yu, X Lei, X Liang, SS Cheng… - Environmental …, 2023 - ACS Publications
Advanced oxidation processes (AOPs) are increasingly applied in water and wastewater
treatment. Understanding the role of reactive species using probes and quenchers is one of …

Oxygen doping of cobalt-single-atom coordination enhances peroxymonosulfate activation and high-valent cobalt–oxo species formation

QY Wu, ZW Yang, ZW Wang… - Proceedings of the …, 2023 - National Acad Sciences
The high-valent cobalt–oxo species (Co (IV)= O) is being increasingly investigated for water
purification because of its high redox potential, long half-life, and antiinterference properties …

Facilely tuning the first-shell coordination microenvironment in iron single-atom for Fenton-like chemistry toward highly efficient wastewater purification

Z Wu, B Huang, X Wang, CS He, Y Liu… - Environmental …, 2023 - ACS Publications
Precisely identifying the atomic structures in single-atom sites and establishing authentic
structure–activity relationships for single-atom catalyst (SAC) coordination are significant …

Elucidation of the mechanistic origin of spin-state-dependent P-doped Fe single-atom catalysts for the oxidation of organic pollutants through peroxymonosulfate …

Y Chai, H Dai, X Duan, Z Sun, F Hu, J Qian… - Applied Catalysis B …, 2024 - Elsevier
In this study, the Fe single-atom catalyst (Fe-NC) was decorated via electronic structure
modulation strategy and P was introduced into the second shell layer to improve the ability …

Fenton-like activity and pathway modulation via single-atom sites and pollutants comediates the electron transfer process

J Guo, Y Wang, Y Shang, K Yin, Q Li… - Proceedings of the …, 2024 - National Acad Sciences
The studies on the origin of versatile oxidation pathways toward targeted pollutants in the
single-atom catalysts (SACs)/peroxymonosulfate (PMS) systems were always associated …

Cu-doped CoOOH activates peroxymonosulfate to generate high-valent cobalt-oxo species to degrade organic pollutants in saline environments

Y Han, C Zhao, W Zhang, Z Liu, Z Li, F Han… - Applied Catalysis B …, 2024 - Elsevier
A Cu doped CoOOH-activated peroxymonosulfate (CoCu10/PMS) process was developed
to enable the generation of Co (IV)= O for efficient oxidation of pollutants in saline water. The …

Mn-Co dual sites relay activation of peroxymonosulfate for accelerated decontamination

Y Yao, C Wang, Y Yang, S Zhang, X Yan, C Xiao… - Applied Catalysis B …, 2023 - Elsevier
Dual atomic catalysts are specially designed for relay activation of peroxymonosulfate
(PMS). Here, a programmable metal-triazolate framework is utilized as a precursor to …

Thermodynamic and kinetic behaviors of persulfate-based electron-transfer regime in carbocatalysis

Y Peng, Q Zhang, W Ren, X Duan, L Ding… - Environmental …, 2023 - ACS Publications
A carbon-based advanced oxidation process is featured for the nonradical electron-transfer
pathway (ETP) from electron-donating organic compounds to activated persulfate …