Stepping out of the blue: from visible to near‐IR triggered photoswitches

Z Zhang, W Wang, M O'Hagan, J Dai… - Angewandte Chemie …, 2022 - Wiley Online Library
Light offers unique opportunities for controlling the activity of materials and biosystems with
high spatiotemporal resolution. Molecular photoswitches are chromophores that undergo …

Photoswitchable diarylethenes: from molecular structures to biological applications

Z Li, X Zeng, C Gao, J Song, F He, T He, H Guo… - Coordination Chemistry …, 2023 - Elsevier
Diarylethene (DAE) photoswitches, known for their reversible photoinduced cyclization and
cycloreversion reactions, have shown great promise in various fields such as optical data …

Recent implementations of molecular photoswitches into smart materials and biological systems

ZL Pianowski - Chemistry–A European Journal, 2019 - Wiley Online Library
Light is a nearly ideal stimulus for molecular systems. It delivers information encoded in the
form of wavelengths and their intensities with high precision in space and time. Light is a …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Towards artificial molecular factories from framework-embedded molecular machines

S Krause, BL Feringa - Nature Reviews Chemistry, 2020 - nature.com
Controlling cooperativity, synchronization, amplification and translation of intermolecular
and intramolecular dynamics over different length scales for applications in stimuli …

Photoswitchable catalysis by a self-assembled molecular cage

RG DiNardi, S Rasheed, SS Capomolla… - Journal of the …, 2024 - ACS Publications
A heteroleptic [Pd2L2L'2] 4+ coordination cage containing a photoswitchable azobenzene-
derived ligand catalyzes the Michael addition reaction between methyl vinyl ketone and …

Reprocessing of covalent adaptable polyamide networks through internal catalysis and ring-size effects

F Van Lijsebetten, Y Spiesschaert… - Journal of the …, 2021 - ACS Publications
Here, we report the introduction of internally catalyzed amide bonds to obtain covalent
adaptable polyamide networks that rely on the dissociation equilibrium between …

Self-switchable polymerization: a smart approach to sequence-controlled degradable copolymers

C Hu, X Pang, X Chen - Macromolecules, 2022 - ACS Publications
In the quest for sustainable development, degradable polymers are attractive alternatives to
traditional fossil-based plastics. As monocomponent degradable polymers often suffer from …

Photoresponsive palladium and nickel catalysts for ethylene polymerization and copolymerization

D Peng, C Chen - Angewandte Chemie, 2021 - Wiley Online Library
In this contribution, we install an azobenzene functionality in olefin polymerization catalysts
and use light to modulate their properties via photoinduced trans–cis isomerization of the …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …