Fluorinated carbenes

DLS Brahms, WP Dailey - Chemical reviews, 1996 - ACS Publications
Replacement of hydrogen by fluorine can have some dramatic effects on the structure,
stability, and reactivity of organic molecules. 1-4 This is especially true for reactive …

The importance of spectroscopy for infrared multiphoton excitation

W Fuss, KL Kompa - Progress in Quantum Electronics, 1981 - Elsevier
It is substantiated by examples that the infrared spectra of molecules in high vibrational
states are similar in width to those of the ground states. Therefore in order to explain …

Emission spectra of CF3 radicals. I. UV and visible emission spectra of CF3 observed in the VUV photolysis and the metastable argon atom reaction of CF3H

M Suto, N Washida - The Journal of Chemical Physics, 1983 - pubs.aip.org
Two new emission bands of the CF3 radical were observed in the UV and visible regions.
These emission bands were produced in the VUV photolysis of CF3H by argon resonance …

The determination of mass transport coefficients and vibrational relaxation rates of species formed in laser photolysis experiments

SE Bialkowski, DS King, JC Stephenson - The Journal of Chemical …, 1980 - pubs.aip.org
A simple analytical solution of the equations which govern the formation, collisional
relaxation, and mass transport rates of species produced in radially symmetric laser …

Spectroscopy and collisional quenching rates for A¯ C2H2 (ν′ 3= 0, 1, 2)

JC Stephenson, JA Blazy, DS King - Chemical physics, 1984 - Elsevier
Laser-excited fluorescence excitation and dispersed fluorescence spectra have been
recorded for the origin and ν′ 3= 1 and 2 levels of A¯ C 2 H 2. Fluorescence decay rates …

Electronic spectroscopy of jet-cooled CFCl: Laser-induced fluorescence, dispersed fluorescence, lifetimes, and C–Cl dissociation barrier

JS Guss, O Votava, SH Kable - The Journal of Chemical Physics, 2001 - pubs.aip.org
Carbenes are species of the general type R–C–R or RvC, where the carbon atom has two
bonding and two nonbonding valence electrons. Their roles in many areas of chemistry such …

Energy partitioning in CO2 laser induced multiphoton dissociations: Energy of X̃/CF2 and X̃/CFCl from CF2CFCl

JC Stephenson, SE Bialkowski, DS King - The Journal of Chemical …, 1980 - pubs.aip.org
We have measured the vibrational (v), rotational (J, K), and translational energy,(ET), of the
X̃ CF2 and X̃ CFCl fragments formed in the CO2 laser induced multiphoton dissociation of …

Photochemistry of CCl3F and CCl2F2 in the 106–200 nm region

T Ibuki, A Hiraya, K Shobatake - The Journal of Chemical Physics, 1989 - pubs.aip.org
The photoabsorption cross sections and fluorescence excitation spectra of CCl3 F and CCl2
F2 were measured using synchrotron radiation at 106–200 nm. The observed absorption …

Laser-induced fluorescence of the CHF radical

MNR Ashfold, F Castano, G Hancock… - Chemical Physics Letters, 1980 - Elsevier
LASER-INDUCED FLUORESCENCE OF THE CHF RADICAL MNR ASHFOLD, F. CA!STAi?O*,
G. HANCOCK and GW KETLEY 1. Introduction Several Page 1 Volume 73, number 3 CHEMICAL …

Fluorescence from photoexcitation of CF3X (X= H, Cl, and Br) at 50–106 nm

LC Lee, JC Han, C Ye, M Suto - The Journal of chemical physics, 1990 - pubs.aip.org
The photoabsorption and fluorescence cross sections ofCF3H, CF3CI, and CF3Br are
measured in the 50-106 nm region using synchrotron radiation. Fluorescence spectra from …