Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications

K Kirakci, MA Shestopalov, K Lang - Coordination Chemistry Reviews, 2023 - Elsevier
The luminescent octahedral molybdenum, tungsten, and rhenium cluster complexes have
attracted a broad interest in the past decades for the design of photofunctional materials …

Phosphorescent NIR emitters for biomedicine: Applications, advances and challenges

PS Chelushkin, JR Shakirova, IS Kritchenkov… - Dalton …, 2022 - pubs.rsc.org
Application of NIR (near-infrared) emitting transition metal complexes in biomedicine is a
rapidly developing area of research. Emission of this class of compounds in the “optical …

Functional materials containing luminescent octahedral halide clusters of molybdenum and tungsten: Diversity of synthetic approaches and binding modes

NA Vorotnikova, YA Vorotnikov… - Coordination Chemistry …, 2024 - Elsevier
The history of the chemistry of halide octahedral cluster complexes began long ago in the
19th century, but to this day these compounds have not lost their topicality or even become …

A water-soluble octahedral molybdenum cluster complex as a potential agent for X-ray induced photodynamic therapy

K Kirakci, TN Pozmogova, AY Protasevich… - Biomaterials …, 2021 - pubs.rsc.org
X-ray-induced photodynamic therapy (X-PDT) has recently evolved into a suitable modality
to fight cancer. This technique, which exploits radiosensitizers producing reactive oxygen …

Hexamolybdenum clusters supported on exfoliated h-BN nanosheets for photocatalytic water purification

MN Ivanova, YA Vorotnikov, EE Plotnikova… - Inorganic …, 2020 - ACS Publications
Nowadays, the development of new effective photocatalytic materials for the purification of
real wastewaters and model systems containing organic molecules constitutes an important …

Stabilization of Octahedral Metal Halide Clusters by Host–Guest Complexation with γ-Cyclodextrin: Toward Nontoxic Luminescent Compounds

AA Ivanov, M Haouas, DV Evtushok… - Inorganic …, 2022 - ACS Publications
γ-Cyclodextrin (γ-CD) interacts in aqueous solution with octahedral halide clusters Na2
[{M6X8} Cl6](M= Mo, W; X= Br, I) to form robust inclusion supramolecular complexes [{M6X8} …

Cotton fabrics modified with molybdenum nanoclusters for photodynamic inactivation of bacteria and viruses

ED Novikova, EV Pronina, YA Vorotnikov… - Journal of …, 2023 - Elsevier
Abstract Design of self-sterilizing materials for protecting surfaces from pathogenic
microorganisms is of profound interest in the medical community. In this study, we have …

Molybdenum iodides–from obscurity to bright luminescence

MA Mikhaylov, MN Sokolov - European Journal of Inorganic …, 2019 - Wiley Online Library
This review is dedicated to the chemistry of Mo iodides. These compounds have a humble
origin, and for a long time their chemistry has been almost completely neglected. Although …

Octahedral molybdenum cluster as a photoactive antimicrobial additive to a fluoroplastic

NA Vorotnikova, AY Alekseev, YA Vorotnikov… - Materials Science and …, 2019 - Elsevier
Finding methods that fight bacterial infection or contamination, while minimising our reliance
on antibiotics is one of the most pressing needs of this century. Although the utilisation of UV …

Optical property trends in a family of {Mo 6 I 8} aquahydroxo complexes

MV Marchuk, NA Vorotnikova, YA Vorotnikov… - Dalton …, 2021 - pubs.rsc.org
Luminescence is one of the key properties of octahedral molybdenum cluster complexes
and the basis for most areas of their possible practical applications. Nevertheless, the factors …