3d-Metal catalyzed N-and C-alkylation reactions via borrowing hydrogen or hydrogen autotransfer
T Irrgang, R Kempe - Chemical reviews, 2018 - ACS Publications
The conservation of our element resources is a fundamental challenge of mankind. The
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …
Advances in one-pot synthesis through borrowing hydrogen catalysis
A Corma, J Navas, MJ Sabater - Chemical reviews, 2018 - ACS Publications
The borrowing hydrogen (BH) principle, also called hydrogen auto-transfer, is a powerful
approach which combines transfer hydrogenation (avoiding the direct use of molecular …
approach which combines transfer hydrogenation (avoiding the direct use of molecular …
Borrowing hydrogen amination reactions: a complex analysis of trends and correlations of the various reaction parameters
Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to
create single C–N bonds, starting from stable and readily available substrates: amines and …
create single C–N bonds, starting from stable and readily available substrates: amines and …
Biobased amines: from synthesis to polymers; present and future
V Froidevaux, C Negrell, S Caillol, JP Pascault… - Chemical …, 2016 - ACS Publications
Amines are key intermediates in the chemical industry due to their nucleophilic characteristic
which confers a high reactivity to them. Thus, they are key monomers for the synthesis of …
which confers a high reactivity to them. Thus, they are key monomers for the synthesis of …
Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation
Q Yang, Q Wang, Z Yu - Chemical Society Reviews, 2015 - pubs.rsc.org
Transition metal-catalyzed substitution of alcohols by N-nucleophiles (or N-alkylation of
amines and related compounds with alcohols) avoids the use of alkylating agents by means …
amines and related compounds with alcohols) avoids the use of alkylating agents by means …
The catalytic amination of alcohols
S Bähn, S Imm, L Neubert, M Zhang… - …, 2011 - Wiley Online Library
In this Minireview, the synthesis of amines by the amination of alcohols, by means of the so‐
called borrowing hydrogen methodology, is presented. Compared to other synthetic …
called borrowing hydrogen methodology, is presented. Compared to other synthetic …
Bio-based amines through sustainable heterogeneous catalysis
The production of amines from biomass is a growing field of interest. Particularly the
amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent …
amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent …
Advances in deep eutectic solvents and water: applications in metal-and biocatalyzed processes, in the synthesis of APIs, and other biologically active compounds
L Cicco, G Dilauro, FM Perna, P Vitale… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Owing to a growing awareness towards environmental impact, the search for “greener”,
safer, and cost-effective solvents able to replace petroleum-derived solvents has never been …
safer, and cost-effective solvents able to replace petroleum-derived solvents has never been …
The give and take of alcohol activation
AJA Watson, JMJ Williams - Science, 2010 - science.org
Alcohols are relatively common starting materials for chemical reactions, even though they
are quite unreactive. For example, reactions that would substitute another functional group …
are quite unreactive. For example, reactions that would substitute another functional group …
Nitrogen-doped graphene nanosheets as metal-free catalysts for aerobic selective oxidation of benzylic alcohols
This work demonstrates the molecular engineering of active sites on a graphene scaffold. It
was found that the N-doped graphene nanosheets prepared by a high-temperature …
was found that the N-doped graphene nanosheets prepared by a high-temperature …