Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

First‐Row Transition‐Metal Catalyzed Acceptorless Dehydrogenation and Related Reactions: A Personal Account

M Subaramanian, G Sivakumar… - The Chemical …, 2021 - Wiley Online Library
The development of sustainable catalytic protocols that circumvent the use of expensive and
precious metal catalysts and avoid toxic reagents plays a crucial role in organic synthesis …

Manganese-catalyzed β-alkylation of secondary alcohols with primary alcohols under phosphine-free conditions

T Liu, L Wang, K Wu, Z Yu - ACS Catalysis, 2018 - ACS Publications
Manganese (I) complexes bearing a pyridyl-supported pyrazolyl-imidazolyl ligand efficiently
catalyzed the direct β-alkylation of secondary alcohols with primary alcohols under …

Nonbifunctional Outer-Sphere Strategy Achieved Highly Active α-Alkylation of Ketones with Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)

XB Lan, Z Ye, M Huang, J Liu, Y Liu, Z Ke - Organic letters, 2019 - ACS Publications
The unusual nonbifunctional outer-sphere strategy was successfully utilized in developing
an easily accessible N-heterocyclic carbene manganese (NHC-Mn) system for highly active …

Ligand-controlled copper (I)-catalyzed cross-coupling of secondary and primary alcohols to α-alkylated ketones, pyridines, and quinolines

DW Tan, HX Li, DL Zhu, HY Li, DJ Young, JL Yao… - Organic …, 2018 - ACS Publications
One hexanuclear Cu (I) cluster of 4, 6-dimethylpyrimidine-2-thiolate efficiently catalyzes the
dehydrogenative cross-coupling of secondary and primary alcohols to α-alkylated ketones …

Nickel-Catalyzed Guerbet Type Reaction: C-Alkylation of Secondary Alcohols via Double (de)Hydrogenation

R Babu, M Subaramanian, SP Midya… - Organic Letters, 2021 - ACS Publications
Acceptorless double dehydrogenative cross-coupling of secondary and primary alcohols
under nickel catalysis is reported. This Guerbet type reaction provides an atom-and a step …

Selective catalytic synthesis of α-alkylated ketones and β-disubstituted ketones via acceptorless dehydrogenative cross-coupling of alcohols

D Bhattacharyya, BK Sarmah, S Nandi… - Organic …, 2021 - ACS Publications
Herein, a phosphine-free pincer ruthenium (III) catalyzed β-alkylation of secondary alcohols
with primary alcohols to α-alkylated ketones and two different secondary alcohols to β …

Catalytic cross-coupling of secondary alcohols

S Thiyagarajan, C Gunanathan - Journal of the American …, 2019 - ACS Publications
Herein, an unprecedented ruthenium (II) catalyzed direct cross-coupling of two different
secondary alcohols to β-disubstituted ketones is reported. Cyclic, acylic, symmetrical, and …

Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex

H Narjinari, N Tanwar, L Kathuria, RV Jasra… - Catalysis Science & …, 2022 - pubs.rsc.org
The β-alkylation of secondary alcohols has been successfully accomplished using earth
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …

Iron-catalyzed α-alkylation of ketones with secondary alcohols: access to β-Disubstituted carbonyl compounds

L Bettoni, S Gaillard, JL Renaud - Organic letters, 2020 - ACS Publications
An iron-catalyzed borrowing hydrogen strategy has been applied in the synthesis of β-
branched carbonyl compounds. Various secondary benzylic and aliphatic alcohols have …