Mass spectrometry in plant metabolomics strategies: from analytical platforms to data acquisition and processing

M Ernst, DB Silva, RR Silva, RZN Vêncio… - Natural product …, 2014 - pubs.rsc.org
Covering: up to 2013. Plant metabolomics is a relatively recent research field that has
gained increasing interest in the past few years. Up to the present day numerous review …

Seasonal variation of the major secondary metabolites present in the extract of Eremanthus mattogrossensis Less (Asteraceae: Vernonieae) leaves

DR Gouvea, L Gobbo-Neto, HT Sakamoto, NP Lopes… - Química …, 2012 - SciELO Brasil
The species Eremanthus mattogrossensis, known as" veludo do cerrado"(cerrado velvet), is
native to the Brazilian Cerrado. Because the amount of metabolites present in plants may be …

Quantum chemical mass spectrometry: ab initio prediction of electron ionization mass spectra and identification of new fragmentation pathways

J Cautereels, M Claeys, D Geldof… - Journal of Mass …, 2016 - Wiley Online Library
The electron ionization mass spectra of four organic compounds are predicted based on the
results of quantum chemical calculations at the DFT/B3LYP/6‐311+ G* level of theory. This …

Analysis and development of structure‐fragmentation relationships in withanolides using an electrospray ionization quadropole time‐of‐flight tandem mass …

SG Musharraf, A Ali, RA Ali, S Yousuf… - Rapid …, 2011 - Wiley Online Library
Structural elucidation and gas‐phase fragmentation of ten withanolides (steroidal lactones)
were studied using a positive ion electrospray ionization quadropole time‐of‐flight mass …

Gas‐phase fragmentation reactions of protonated cocaine: new details to an old story

HJ Dias, MVB Bento, ÉH da Silva… - Journal of Mass …, 2018 - Wiley Online Library
We have used a combination of multiple stage mass spectrometry (MSn) experiments,
hydrogen/deuterium exchange experiments, and thermochemical data estimated by …

Tandem Mass Spectrometry Imaging and in Situ Characterization of Bioactive Wood Metabolites in Amazonian Tree Species Sextonia rubra

T Fu, D Touboul, S Della-Negra, E Houël… - Analytical …, 2018 - ACS Publications
Driven by a necessity for confident molecular identification at high spatial resolution, a new
time-of-flight secondary ion mass spectrometry (TOF-SIMS) tandem mass spectrometry …

Electrospray ionization tandem mass spectrometry of labdane‐type acid diterpenes

GP Aguiar, EJ Crevelin, HJ Dias… - Journal of Mass …, 2018 - Wiley Online Library
Copaifera (Leguminoseae) species produce a commercially interesting oleoresin that
displays several biological activities, including antimicrobial and anti‐inflammatory …

Electrospray ionization tandem mass spectrometry analysis of isopimarane diterpenes from Velloziaceae

A da Cunha Pinto, R Vessecchi… - Rapid …, 2016 - Wiley Online Library
Rationale The study of natural products by electrospray ionization tandem mass
spectrometry (ESI‐MS/MS) is an important strategy for the characterization of the major …

Organocatalytic Approach for Short Asymmetric Synthesis of (R)-Paraconyl Alcohol: Application to the Total Syntheses of IM-2, SCB2, and A-Factor γ-Butyrolactone …

AM Sarkale, A Kumar, C Appayee - The Journal of Organic …, 2018 - ACS Publications
(R)-Paraconyl alcohol is found to be a key intermediate for the syntheses of many γ-
butyrolactone autoregulators. The chiral auxiliary approach and enzymatic resolution are the …

Intramolecular hydrogen transfer reactions of thiyl radicals from glutathione: formation of carbon-centered radical at Glu, Cys, and Gly

O Mozziconacci, TD Williams… - Chemical research in …, 2012 - ACS Publications
Glutathione thiyl radicals (GS•) were generated in H2O and D2O by either exposure of GSH
to AAPH, photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG …