Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

The bond activation chemistry of B (C6F5) 3 and related electron-deficient boranes is
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …

Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

Dearomatized N‐heterocycles are an important class of structural motifs for organic
synthesis and chemical biology. The catalytic dearomative reduction of unactivated N …

An acceptorless dehydrogenation of heterocycles catalyzed by frustrated Lewis pairs (FLPs)
was developed. Oxidation with concomitant liberation of molecular hydrogen proceeded in …

Conspectus The activation of molecular hydrogen by main-group element catalysts is an
extremely important approach to metal-free hydrogenations. These so-called frustrated …

Described herein is the development of an unprecedented route to bridged sila-N-
heterocycles via B (C6F5) 3-catalyzed cascade silylation of N-aryl piperidines with …

Recent years have witnessed marked progress in the efficient synthesis of various
enantioenriched 1, 2, 3, 4‐tetrahydroquinoxalines. However, enantio‐and diastereoselective …

Dehydrocoupling reactions, ie reactions involving elimination of H2 between two E–H
bonds, provide a clean route to E–E bonds within the main group. The products afforded …