Methods utilizing first-row transition metals in natural product total synthesis

JE Zweig, DE Kim, TR Newhouse - Chemical Reviews, 2017 - ACS Publications
First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …

Characteristic metabolites of Hypericum plants: their chemical structures and biological activities

N Tanaka, Y Kashiwada - Journal of natural medicines, 2021 - Springer
Plants belonging to the genus Hypericum (Hypericaceae) are recognized as an abundant
source of natural products with interesting chemical structures and intriguing biological …

Direct radical acetoxyphosphorylation of styrenes mediated by manganese (III)

SF Zhou, DP Li, K Liu, JP Zou… - The Journal of Organic …, 2015 - ACS Publications
Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III) | The Journal of
Organic Chemistry ACS ACS Publications C&EN CAS Find my institution Log In The Journal of …

An Yb (OTf) 3 and visible light relay catalyzed [3+ 2] cycloaddition/[3, 3]-rearrangement/[4+ 2] cycloaddition in one pot to prepare oxazonine-fused endoperoxides

XP Ma, CM Nong, YF Liang, PP Xu, XY Guo… - Green …, 2020 - pubs.rsc.org
We report a relay catalysis for the highly stereoselective synthesis of densely substituted
oxazonine-fused endoperoxides in good yields. This domino reaction is based on an Yb …

Visible‐Light Photoredox Catalysis Enables the Biomimetic Synthesis of Nyingchinoids A, B, and D, and Rasumatranin D

JD Hart, L Burchill, AJ Day, CG Newton… - Angewandte …, 2019 - Wiley Online Library
The total synthesis of nyingchinoids A and B has been achieved through successive
rearrangements of a 1, 2‐dioxane intermediate that was assembled using a visible‐light …

Total synthesis of calophyline A

G Li, X Xie, L Zu - Angewandte Chemie, 2016 - Wiley Online Library
Reported herein is the total synthesis of calophyline A, an indoline natural product
possessing distinct ring connectivity which has not been synthesized previously. The …

Hydrofunctionalization of alkenols triggered by the addition of diverse radicals to unactivated alkenes and subsequent remote hydrogen atom translocation

N Wang, L Ye, ZL Li, L Li, Z Li, HX Zhang… - Organic Chemistry …, 2018 - pubs.rsc.org
Diverse anti-Markovnikov hydrofunctionalization of alkenols triggered by the addition of S-, P-
, and C-centered radicals to alkenes followed by intramolecular 1, 5 (6)-hydrogen atom …

Synthesis of desacyl furanmonogones A and B

D Li, J Yang, B Liu, J Gong, Z Yang - Organic Letters, 2021 - ACS Publications
A strategy for the stereoselective synthesis of desacyl furanmonogones A and B has been
achieved. The key steps in this synthesis are (1) an Fe (ClO4) 3-mediated oxidative radical …

Hyperxylones A and B, two polycyclic polyprenylated acylphloroglucinols with a benzoyl substituted bicyclo [3.2. 1] octane core from Hypericum beanii

XY Li, RR Dong, MM Nan, XL Wang, TJ Cao, P Ying… - Fitoterapia, 2023 - Elsevier
Two new polycyclic polyprenylated acylphloroglucinols (PPAPs) possessing a rare benzoyl
substituted bicyclo [3.2. 1] octane core, hyperxylones A (1) and B (2), along with three new …

[PDF][PDF] Prenylated acylphloroglucinols and meroterpenoids from Hypericum plants

N Tanaka, J Kobayashi - Heterocycles, 2015 - triggered.edina.clockss.org
Hypericum plants {family Clusiaceae (APG: Hypericaceae)} are known to be a rich source of
prenylated acylphloroglucinols (PAPs), some of which have attracted attention as new drug …