Electrochemically driven hydrogen atom transfer (HAT) catalysis provides a complementary
approach for the transformation of redox-inactive substrates that would be inaccessible to …

Conspectus Cyclometalated iridium (III) complexes are frequently employed in organic light
emitting diodes, and they are popular photocatalysts for solar energy conversion and …

The synthesis of weak chemical bonds at or near thermodynamic potential is a fundamental
challenge in chemistry, with applications ranging from catalysis to biology to energy science …

Photoinduced symmetry-breaking charge separation (SB-CS) processes offer the possibility
of harvesting solar energy by electron transfer between identical molecules. Here, we …

Although metal complexes are known to split dinitrogen at ambient temperature and
pressure, the synthesis of ammonia from these compounds with H2 as the terminal reductant …

A catalytic system based on earth-abundant elements that efficiently hydrogenates aryl
olefins using visible light as the driving-force and H2O as the sole hydrogen atom source is …

Oxidase‐type oxidation is an attractive strategy in organic synthesis due to the use of O2 as
the terminal oxidant. Organic photocatalysis can effect metal‐free oxidase chemistry …

The photochemical formation of metal hydride complexes or organic hydride compounds
plays an important role in the conversion of light energy into the formation of chemical bonds …

The harvesting of visible light is a powerful strategy for the synthesis of weak chemical
bonds involving hydrogen that are below the thermodynamic threshold for spontaneous H2 …

C–N bond formation is integral to modern chemical synthesis due to the ubiquity of nitrogen
heterocycles in small-molecule pharmaceuticals and agrochemicals. Alkene hydroamination …