The addition of an allylic organometallic compound to a carbonyl compound or an imine is of
great synthetic interest because in this reaction together with a new functionality (hydroxyl or …

The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

During the last century, organometallic reagents prepared from main group metals, 1 such
as organolithium, organomagnesium, and organozinc compounds, have played a central …

Chiral BINOL-derived diols catalyze the enantioselective asymmetric allylboration of acyl
imines. The reaction requires 15 mol%(S)-3, 3 '-Ph2-BINOL as the catalyst and …

A delicate interplay of several kinetically labile ligands is required for reactions that proceed
through serial ligand catalysis mechanisms. An investigation of the disruption of this balance …

A catalytic method for enantioselective synthesis of homoallylamides through Cu-catalyzed
reactions of stable and easily accessible (pinacolato) allylborons with aryl-, heteroaryl-, alkyl …

This review deals with organic reactions which are promoted by indium metal or indium
salts, with a focus on recent advances in stoichiometric and catalytic pathways. Applications …

Oxovanadium complex bearing 3-hydroxypicolinic acid (H2hpic), that is, VO (Hhpic) 2,
successfully catalyzes a highly selective oxidation of benzylamines to the corresponding N …

“On the seashore of endless worlds, children meet...... they know not how to swim, they know
not how to cast nets. Pearl fishers diVe for pearls; merchants sail in their ships, while …

Thia− Fries rearrangement of BINOL perfluoroalkylsulfonates affords readily derivatized
novel mono-and disulfone ligands in just two steps from enantiomerically pure BINOL …