Cycloaddition chemistry of organic molecules with semiconductor surfaces

RJ Hamers, SK Coulter, MD Ellison… - Accounts of chemical …, 2000 - ACS Publications
Recent investigations have shown that cycloaddition reactions, widely used in organic
chemistry to form ring compounds, can also be applied to link organic molecules to the (001) …

Attachment chemistry of organic molecules on Si (111)-7× 7

F Tao, GQ Xu - Accounts of chemical research, 2004 - ACS Publications
Molecular attachment chemistry is emerging as an important approach to tailor the chemical,
physical, and mechanical properties of silicon surfaces, as well as to incorporate organic …

Functionalization of nanoscale diamond powder: fluoro-, alkyl-, amino-, and amino acid-nanodiamond derivatives

Y Liu, Z Gu, JL Margrave… - Chemistry of …, 2004 - ACS Publications
The reaction of nanoscale diamond (ND) powder with an elemental fluorine/hydrogen
mixture at temperatures varying from 150 to 470° C resulted in the high degree of ND …

Attaching organic layers to semiconductor surfaces

SF Bent - The Journal of Physical Chemistry B, 2002 - ACS Publications
Methods that can be used to tailor the surface properties of semiconductors will become
increasingly important as new applications for semiconductor-based materials continue to …

Proton transfer reactions on semiconductor surfaces

C Mui, JH Han, GT Wang, CB Musgrave… - Journal of the American …, 2002 - ACS Publications
The concept of proton affinity on semiconductor surfaces has been explored through an
investigation of the chemistry of amines on the Ge (100)-2× 1, Si (100)-2× 1, and C (100)-2× …

First-principles investigation of hydrogen-related reactions on (100)–(2× 1): H diamond surfaces

EY Guillaume, DEP Vanpoucke, R Rouzbahani… - Carbon, 2024 - Elsevier
Hydrogen radical attacks and subsequent hydrogen migrations are considered to play an
important role in the atomic-scale mechanisms of diamond chemical vapour deposition …

Molecular surface functionalization of carbon materials via radical-induced grafting of terminal alkenes

Y Zhang, AA Tamijani, ME Taylor, B Zhi… - Journal of the …, 2019 - ACS Publications
Formation of functional monolayers on surfaces of carbon materials is inherently difficult
because of the high bond strength of carbon and because common pathways such as SN2 …

Cycloaddition chemistry at surfaces: reaction of alkenes with the diamond (001)-2× 1 surface

JS Hovis, SK Coulter, RJ Hamers… - Journal of the …, 2000 - ACS Publications
The (001) surfaces of diamond, silicon, and germanium share a similar bonding motif in
which pairs of atoms bond to each other via a strong σ bond and a weaker π bond, forming …

Surface migration in diamond growth

M Frenklach, S Skokov - The Journal of Physical Chemistry B, 1997 - ACS Publications
Growth of diamond has usually been discussed without invoking any form of surface
diffusion. Our recent theoretical results identified, however, that bridging CH2 and CCH2 …

Functionalization of diamond (100) by Diels− Alder chemistry

GT Wang, SF Bent, JN Russell, JE Butler… - Journal of the …, 2000 - ACS Publications
Diels-Alder reactions are powerful, widely used reactions for CC bond formation. In addition
to the well-known Diels-Alder reactions in the solution phase, it has been shown that they …