The surface chemistry of cerium oxide

DR Mullins - Surface Science Reports, 2015 - Elsevier
This review covers the structure of, and chemical reactions on, well-defined cerium oxide
surfaces. Ceria, or mixed oxides containing ceria, are critical components in automotive …

Well-ordered transition metal oxide layers in model catalysis–a series of case studies

H Kuhlenbeck, S Shaikhutdinov, HJ Freund - Chemical reviews, 2013 - ACS Publications
The development of surface science of solid metal surfaces during the last 50 years has
been intimately connected with heterogeneous catalysis and culminated in the Nobel prize …

Counting electrons on supported nanoparticles

Y Lykhach, SM Kozlov, T Skála, A Tovt, V Stetsovych… - Nature materials, 2016 - nature.com
Electronic interactions between metal nanoparticles and oxide supports control the
functionality of nanomaterials, for example, the stability, the activity and the selectivity of …

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles

GN Vayssilov, Y Lykhach, A Migani, T Staudt… - Nature materials, 2011 - nature.com
Interactions of metal particles with oxide supports can radically enhance the performance of
supported catalysts. At the microscopic level, the details of such metal–oxide interactions …

Reactivity of Hydroxyls and Water on a CeO2(111) Thin Film Surface: The Role of Oxygen Vacancy

B Chen, Y Ma, L Ding, L Xu, Z Wu… - The Journal of …, 2013 - ACS Publications
The interaction of atomic hydrogen and H2O with stoichiometric and partially reduced CeO2
(111) thin films deposited on a Cu (111) substrate was investigated by temperature …

Atomically dispersed Pd, Ni, and Pt species in ceria-based catalysts: principal differences in stability and reactivity

A Neitzel, A Figueroba, Y Lykhach… - The Journal of …, 2016 - ACS Publications
We have investigated the stability and the reactivity of atomically dispersed Pt, Pd, and Ni
species on nanostructured CeO2 films by means of synchrotron radiation photoelectron …

Near ambient pressure XPS investigation of the interaction of ethanol with Co/CeO2 (1 1 1)

L Óvári, SK Calderon, Y Lykhach, J Libuda… - Journal of catalysis, 2013 - Elsevier
Near ambient pressure X-ray photoelectron spectroscopy was applied to study the
interaction of ethanol (CH 3 CH 2 OH) with a well-ordered CeO 2 (1 1 1) film on Cu (1 1 1) …

Methane activation by platinum: Critical role of edge and corner sites of metal nanoparticles

F Viñes, Y Lykhach, T Staudt… - … A European Journal, 2010 - Wiley Online Library
Complete dehydrogenation of methane is studied on model Pt catalysts by means of state‐of‐
the‐art DFT methods and by a combination of supersonic molecular beams with high …

Water chemistry on model ceria and Pt/ceria catalysts

Y Lykhach, V Johanek, HA Aleksandrov… - The Journal of …, 2012 - ACS Publications
We have studied the interaction of water with stoichiometric CeO2 (111)/Cu (111), partially
reduced CeO2–x/Cu (111), and Pt/CeO2/Cu (111) model catalysts by means of synchrotron …

Ceria reoxidation by CO2: A model study

T Staudt, Y Lykhach, N Tsud, T Skála, KC Prince… - Journal of …, 2010 - Elsevier
The activation of CO2 on ceria-based catalysts opens chemical routes to the use of CO2 as
an oxidizing agent. Toward a better understanding of the underlying surface reactions, we …