Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Photomediated Giese reactions are at the forefront of radical chemistry, much like the
classical tin‐mediated Giese reactions were nearly forty years ago. With the global …

Carboxylic acids, including amino acids (AAs), have been widely used as reagents for
decarboxylative couplings. In contrast to previous decarboxylative couplings that release …

Chemists extensively use free radical reactivity for applications in organic synthesis,
materials science, and life science. Traditionally, generating radicals requires strategies that …

Deuterium labelled compounds are of significant importance in chemical mechanism
investigations, mass spectrometric studies, diagnoses of drug metabolisms, and …

Carbazole/cyanobenzene photocatalysts promote the direct isotopic carboxylate exchange
of C (sp3) acids with labeled CO2. Substrates that are not compatible with transition-metal …

Conspectus The use of photocatalysis in organic chemistry has encountered a surge of
novel transformations since the start of the 21st century. The majority of these …

The decatungstate anion [W10O32] 4–is a widely used photocatalyst for promoting
hydrogen atom transfer (HAT) reactions. The mechanism implicated in the activation of …

A facile sunlight-induced derivatization of heteroaromatics via photocatalyzed C–H
functionalization in amides, ethers, alkanes and aldehydes is described …