Das zentrale Thema der Organischen Chemie ist die Knüpfung von Kohlenstoff-Kohlenstoff-
Bindungen-Schlüsselschritte im Aufbau komplexer Moleküle aus einfachen Vorstufen. In der …

The importance of tandem reactions is evident--besides their pragmatic value, they have an
aesthetic appeal. The author presents a survey of these reactions that will rivet the attention …

Functional-group transformations leading to carbon-carbon bond formation are linchpins of
synthetic en-deavors. With the aid of transition-metal catalysts or reagents, the increasing …

Reaction of 2, 3-allenols with PhMe2SiZnCl or Ph2MeSiZnCl under catalysis of IPrCuCl or
SIPrCuCl was carried out, affording 2-silyl-1, 3-butadienes. Secondary and tertiary 2, 3 …

Recent advances on the synthetic applications of the dithioacetal functionality are briefly
reviewed. Nickel-catalyzed silylolefination reaction has led to the synthesis of a range of silyl …

Two types of regio-and stereoselective hydrosilylation reactions of 1, 3-enynes catalyzed by
Co complexes were developed. Dppf-CoCl2 is applicable for 3, 4-hydrosilylation of 4-aryl …

Introduction of spacers between well-defined chromophores in the polymeric chain can
occasionally increase the processibility, and in the mean time, the emission wavelength can …

This work describes the first formal cycloaddition reaction of photogenerated nucleophilic
carbenes derived from acylsilanes with electrophilic dienes. The resulting transient donor …

An efficient conversion of bis-silylated dienes and trienes into polyenylsilanes by cross-
coupling reactions is described. The aryl substituted polyenes are synthesized by ipso …

Transition metal‐catalyzed addition of bis‐silyl hydride to bis‐alkyne is widely used for the
synthesis of alt‐silylene‐divinyl‐linker copolymer. When the linker for connecting two silyl …