In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

For molecules with a singlet ground state, the population of triplet states is mainly possible
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

Selective functionalization of inactive C (sp3)–F bonds to prepare medicinally interesting
aryldifluoromethylated compounds remains challenging. One promising route is the …

Electrochemistry grants direct access to reactive intermediates (radicals and ions) in a
controlled fashion toward selective organic transformations. This feature has been …

We report the first palladium hydride enabled hydroalkenylation of strained molecules. This
new mild protocol proceeds via a regio-and chemoselective hydropalladation step, followed …

Selective functionalization of ubiquitous unactivated C–H bonds is a continuous quest for
synthetic organic chemists. In addition to transition metal catalysis, which typically operates …

Transition metal–catalyzed coupling reactions have become one of the most important tools
in modern synthesis. However, an inherent limitation to these reactions is the need to …

A visible light-induced palladium-catalyzed homologative three-component synthesis of
allylic amines has been developed. This protocol proceeds via a unique mechanism …