Towards an understanding of induced-charge electrokinetics at large applied voltages in concentrated solutions

MZ Bazant, MS Kilic, BD Storey, A Ajdari - Advances in colloid and interface …, 2009 - Elsevier
The venerable theory of electrokinetic phenomena rests on the hypothesis of a dilute
solution of point-like ions in quasi-equilibrium with a weakly charged surface, whose …

Dynamic adsorption/desorption process model for capacitive deionization

PM Biesheuvel, B van Limpt… - The journal of physical …, 2009 - ACS Publications
In capacitive deionization (CDI), an electrical potential difference is applied across
oppositely placed electrodes, resulting in the adsorption of ions from aqueous solution and a …

Ion current rectification in asymmetric charged bilayer nanochannels

Z Liu, X Liu, Y Wang, D Yang, C Li - Electrochimica Acta, 2022 - Elsevier
At present, little attention has been paid to the ion current rectification (ICR) performance in
the bilayer nanochannel with non-uniform charge distribution, which has the similar …

Diffuse-charge effects on the transient response of electrochemical cells

M Van Soestbergen, PM Biesheuvel, MZ Bazant - Physical Review E …, 2010 - APS
We present theoretical models for the time-dependent voltage of an electrochemical cell in
response to a current step, including effects of diffuse charge (or “space charge”) near the …

Optimizing microstructure of polyelectrolyte ion exchange membrane for electrodialysis

J Cheng, W Zhou, M Zhu, Z Zhang, Y Lu, Y Chen… - Chemical Engineering …, 2023 - Elsevier
In electrodialysis process, polyelectrolyte multilayer membranes (PEMMs) are introduced as
a novel ion exchange membrane (IEM), as they can adjust different membrane structures …

Self-consistent approach to global charge neutrality in electrokinetics: A surface potential trap model

L Wan, S Xu, M Liao, C Liu, P Sheng - Physical Review X, 2014 - APS
In this work, we treat the Poisson-Nernst-Planck (PNP) equations as the basis for a
consistent framework of the electrokinetic effects. The static limit of the PNP equations is …

Inhibition of electrokinetic ion transport in porous materials due to potential drops induced by electrolysis

K Kamran, M Van Soestbergen, HP Huinink, L Pel - Electrochimica Acta, 2012 - Elsevier
In this work we present non-destructive measurements of sodium ion concentration profiles
during the electrokinetic removal of sodium chloride from porous materials using Nuclear …

Theory of aluminum metallization corrosion in microelectronics

M Van Soestbergen, A Mavinkurve, RTH Rongen… - Electrochimica …, 2010 - Elsevier
We present a time-dependent numerical model for corrosion in microelectronics, focusing on
aluminum bondpads, which can be very beneficial for the design as well as the …

Analytical solution of the Poisson–Nernst–Planck equations in the linear regime at an applied dc-voltage

A Golovnev, S Trimper - The Journal of chemical physics, 2011 - pubs.aip.org
The analytical solution of the Poisson–Nernst–Planck equations is found in the linear regime
as response to a dc-voltage. In deriving the results a new approach is suggested, which …

[HTML][HTML] Elucidating the large variation in ion diffusivity of microelectronic packaging materials

A Herrmann, M van Soestbergen, SJF Erich… - Microelectronics …, 2022 - Elsevier
The risk of corrosion poses a challenge to meet the stringent reliability requirements of
microelectronic devices that are used in harsh environments. Microelectronic devices are …