Synthesis of α, β-unsaturated carbonyl compounds by carbonylation reactions

S Zhang, H Neumann, M Beller - Chemical Society Reviews, 2020 - pubs.rsc.org
α, β-Unsaturated carbonyl compounds are key building blocks in organic chemistry. Their
catalytic synthesis has received significant attention during the past decades. Among the …

Transition-metal-catalyzed enantioselective C− H silylation

Y Ge, X Huang, J Ke, C He - Chem Catalysis, 2022 - cell.com
Organosilanes are important and valuable compounds that have found widespread
applications in the fields of organic chemistry, agrochemistry, medicinal chemistry, and …

A Zr-MOF nanoflower sensor and its mixed-matrix membrane for the highly sensitive detection of nitroaromatics

H Xu, F Zhong, F Chen, TX Luan, P Li, S Xu… - Journal of Materials …, 2022 - pubs.rsc.org
A new luminescent metal–organic framework nanoflower material CJLU-1 (Zr6 (μ3-O) 4 (μ3-
OH) 4 (OH) 6 (TCA) 2 (H2O) 6)(H3TCA= tri-carboxylic acids 4, 4′, 4′′-nitrilotribenzoic …

Highly Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of Styrenes and 1,3-Dienes with CO2

YY Gui, N Hu, XW Chen, LL Liao, T Ju… - Journal of the …, 2017 - ACS Publications
Herein, we report a highly regio-and enantioselective copper-catalyzed reductive
hydroxymethylation of styrenes and 1, 3-dienes with 1 atm of CO2. Diverse important chiral …

Copper-catalyzed desymmetrization of prochiral silanediols to silicon-stereogenic silanols

J Gao, PL Mai, Y Ge, W Yuan, Y Li, C He - ACS Catalysis, 2022 - ACS Publications
Despite the growing demand for the enantioenriched silicon-stereogenic silanols in
materials science, medicinal chemistry, and modern synthetic chemistry, the catalytic …

Enantioselective Hydroxylation of Dihydrosilanes to Si‐Chiral Silanols Catalyzed by In Situ Generated Copper (II) Species

W Yang, L Liu, J Guo, SG Wang, JY Zhang… - Angewandte …, 2022 - Wiley Online Library
Catalytic enantioselective hydroxylation of prochiral dihydrosilanes with water is expected to
be a highly efficient way to access Si‐chiral silanols, yet has remained unknown up to date …

Catalytic Asymmetric dehydrogenative Si–H/N–H coupling: synthesis of silicon-stereogenic silazanes

MM Liu, Y Xu, C He - Journal of the American Chemical Society, 2023 - ACS Publications
Despite growing progress in the construction of silazanes, the catalytic asymmetric synthesis
of silicon-stereogenic silazanes is significantly less explored and remains a considerable …

Copper‐Catalyzed Chemoselective Asymmetric Hydrogenation of C= O Bonds of Exocyclic α, β‐Unsaturated Pentanones

J Guan, J Chen, Y Luo, L Guo… - Angewandte Chemie …, 2023 - Wiley Online Library
A highly chemoselective earth‐abundant transition metal copper catalyzed asymmetric
hydrogenation of C= O bonds of exocyclic α, β‐unsaturated pentanones was realized using …

Atroposelective Silylation of 1, 1′‐Biaryl‐2, 6‐diols by a Chiral Counteranion Directed Desymmetrization Enhanced by a Subsequent Kinetic Resolution

M Zhu, HJ Jiang, I Sharanov, E Irran… - Angewandte Chemie …, 2023 - Wiley Online Library
A desymmetrizing silylation of aromatic diols is reported. The previously unknown
asymmetric silyl ether formation of phenol derivatives is achieved by applying List's …

Using a nitrogen-centered radical as a selective mediator in electrochemical C (sp3)-H amination

Y Liang, X Zhan, F Li, H Bi, W Fan, S Zhang, MB Li - Chem Catalysis, 2023 - cell.com
Nitrogen-centered radicals are versatile intermediates, and they have been widely explored
in organic synthesis. However, the catalytic role of these species has received far less …