Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Conjugated nanohoops incorporating donor, acceptor, hetero‐or polycyclic aromatics

M Hermann, D Wassy, B Esser - Angewandte Chemie, 2021 - Wiley Online Library
In the last 13 years several synthetic strategies were developed that provide access to [n]
cycloparaphenylenes ([n] CPPs) and related conjugated nanohoops. A number of potential …

An unexpected dual-emissive luminogen with tunable aggregation-induced emission and enhanced chiroptical property

X Zhang, H Liu, G Zhuang, S Yang, P Du - Nature Communications, 2022 - nature.com
In the literature, organic materials with both aggregation-induced emission (AIE) and
aggregation-caused quenching (ACQ) effects that can emit with multiple bands both in the …

Infinitene: a helically twisted figure-eight [12] circulene topoisomer

M Krzeszewski, H Ito, K Itami - Journal of the American Chemical …, 2021 - ACS Publications
New forms of molecular nanocarbon particularly looped polyarenes adopting various
topologies contribute to the fundamental science and practical applications. Here we report …

Synthesis of π-conjugated chiral organoborane macrocycles with blue to near-infrared emissions and the diradical character of cations

F Zhao, J Zhao, H Liu, Y Wang, J Duan… - Journal of the …, 2023 - ACS Publications
Highly emissive π-conjugated macrocycles with tunable circularly polarized luminescence
(CPL) have sparked theoretical and synthetic interests in recent years. Herein, we report a …

The supramolecular chemistry of strained carbon nanohoops

Y Xu, M von Delius - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Since 1996, a growing number of strained macrocycles, comprising only sp2‐or sp‐
hybridized carbon atoms within the ring, have become synthetically accessible, with the [n] …

Circularly Polarized Luminescence in Chiral π‐Conjugated Macrocycles

M Hasegawa, Y Nojima, Y Mazaki - ChemPhotoChem, 2021 - Wiley Online Library
The design and synthesis of novel π‐conjugated macrocycles have been an attractive topic
in synthetic chemistry and material and supramolecular chemistry. The distortion caused by …

Azahelicene‐fused BODIPY analogues showing circularly polarized luminescence

C Maeda, K Nagahata, T Shirakawa… - Angewandte …, 2020 - Wiley Online Library
Helical carbazole‐based BODIPY analogues were readily synthesized via aza [7] helicenes.
The structures of azahelicene‐incorporated BF2 dyes were elucidated by x‐ray diffraction …

Lemniscular carbon nanohoops with contiguous conjugation from planar chiral [2.2] paracyclophane: influence of the regioselective synthesis on topological chirality

J He, MH Yu, Z Lian, YQ Fan, SZ Guo, XN Li… - Chemical …, 2023 - pubs.rsc.org
We report herein the regioselective synthesis of all-carbon lemniscular nanohoops bis-po-
CC and bis-pm-TC by the rational control of ring closures at the different positions of planar …

A Fused [5] Helicene Dimer with a Figure‐Eight Topology: Synthesis, Chiral Resolution, and Electronic Properties

Q Zhou, X Hou, J Wang, Y Ni, W Fan, Z Li… - Angewandte …, 2023 - Wiley Online Library
Chiral shape‐persistent molecular nanocarbons are promising chiroptical materials; their
synthesis, however, remains a big challenge. Herein, we report the facile synthesis and …