Main group molecular switches with swivel bifurcated to trifurcated hydrogen bond mode of action
G Hum, SJI Phang, HC Ong, F León… - Journal of the …, 2023 - ACS Publications
Artificial molecular machines have captured the full attention of the scientific community
since Jean-Pierre Sauvage, Fraser Stoddart, and Ben Feringa were awarded the 2016 …
since Jean-Pierre Sauvage, Fraser Stoddart, and Ben Feringa were awarded the 2016 …
Orthogonality in main group compounds: a direct one-step synthesis of air-and moisture-stable cyclophosphazanes by mechanochemistry
Mechanochemistry has been established to be an environmentally-friendly way of
conducting reactions in a solvent-free manner. The development of mechanochemical …
conducting reactions in a solvent-free manner. The development of mechanochemical …
Conformational control in main group phosphazane anion receptors and transporters
Anion binding by receptor molecules is a central field of modern chemistry which impacts
areas of catalysis as well as biological and materials chemistry. As binding often requires …
areas of catalysis as well as biological and materials chemistry. As binding often requires …
Tailoring the binding properties of phosphazane anion receptors and transporters
The binding and sensing of anions is an important cross-disciplinary field, which impacts
broad areas such as biology, supramolecular chemistry and catalysis. To date, however, this …
broad areas such as biology, supramolecular chemistry and catalysis. To date, however, this …
Assembly of metallo-macrocycles through reductive C–C coupling of alkylnitriles by an Mg–Mg-bonded compound
Y Xue, J Wang, Y Shi, W Xu, Y Zhao, B Wu… - Dalton …, 2022 - pubs.rsc.org
Low-valent metal complexes have attracted much research interest owing to their novel
reactivities toward small molecules. Herein the reactivity of the α-diimine-ligated, Mg–Mg …
reactivities toward small molecules. Herein the reactivity of the α-diimine-ligated, Mg–Mg …
N‐bridged acyclic trimeric poly‐cyclodiphosphazanes: highly tuneable cyclodiphosphazane building blocks
We have synthesized a completely new family of acyclic trimeric cyclodiphosphazane
compounds comprising NH, NiPr, NtBu and NPh bridging groups. In addition, the first NH …
compounds comprising NH, NiPr, NtBu and NPh bridging groups. In addition, the first NH …
Catechol and 1, 2, 4, 5-tetrahydroxybenzene functionalized cyclodiphosphazane ligands: synthesis, structural studies, and transition metal complexes
Syntheses of two novel cyclodiphosphazane derivatives appended on catechol and 1, 2, 4,
5-tetrahydroxy benzene,[{(μ-N (tBu) P) 2 (C6H4O2)}](1) and [{((μ-N (tBu) P) 2) 2 (μ …
5-tetrahydroxy benzene,[{(μ-N (tBu) P) 2 (C6H4O2)}](1) and [{((μ-N (tBu) P) 2) 2 (μ …
Pre-arranged building block approach for the orthogonal synthesis of an unfolded tetrameric organic–inorganic phosphazane macrocycle
Inorganic macrocycles remain challenging synthetic targets due to the limited number of
strategies reported for their syntheses. Among these species, large fully inorganic …
strategies reported for their syntheses. Among these species, large fully inorganic …
A chiral phosphazane reagent strategy for the determination of enantiomeric excess of amines
AJ Peel, A Terzopoulos, RB Jethwa, D Choudhury… - Chemical …, 2022 - pubs.rsc.org
Methods for measuring enantiomeric excess (ee) of organic molecules by NMR
spectroscopy provide rapid analysis using a standard technique that is readily available …
spectroscopy provide rapid analysis using a standard technique that is readily available …
Guest Binding via N− H⋅⋅⋅ π Bonding and Kinetic Entrapment by an Inorganic Macrocycle
AJ Plajer, FJ Rizzuto, HC Niu, S Lee… - Angewandte Chemie …, 2019 - Wiley Online Library
Modern supramolecular chemistry is overwhelmingly based on non‐covalent interactions
involving organic architectures. However, the question of what happens when you depart …
involving organic architectures. However, the question of what happens when you depart …