The complexation of two equivalents of a cyclic (alkyl)(amino) carbene (CAAC) to
tetrabromodiborane, followed by reduction with four equivalents of sodium naphthalide, led …

Inspired by experimentally discovering ferromagnetism and ferroelectricity in two-
dimensional (2D) CrGeTe3 and CuInP2S6 with similar geometric structures, respectively, we …

Recently, the NHC→ BB← NHC molecule 1 has been published in Science where it is
described as a stabilized B2 molecule in its 1Σ excited state (B2*)(NHC= N-heterocyclic …

The cyclic alkyl (amino) carbene (cAAC) 1 reacted with SiI4 in toluene, affording the cAAC-
silicon tetraiodide complex [(cAACMe) SiI4](2, cAACMe=: C (CH2)(CMe2) 2NAr, Ar= 2, 6-i …

Bis (chlorotetrylene) s of Si, Ge, and Sn have been synthetically realized starting from the
backbone‐bridged bis (amidine) 1. Double deprotonation of 1 and subsequent reaction with …

A germylene/borane Lewis pair (2) was prepared from a 1, 1‐carboboration of amidinato
phenylethynylgermylene (1) by B (C6F5) 3. Compound 2 reacted with iPrNCO and (4 …

A systematic theoretical study was conducted on the triel bonds (TrBs) within the TrX3··· Be
(CO) 3 complexes (Tr= B, Al, Ga, In, Tl; X= H, F, Cl, Br, I). The interaction energies of these …

Dinuclear low‐valent compounds of the heavy main group elements are rare species owing
to their intrinsic reactivity. However, they represent desirable target molecules due to their …

Heavier tetrylenes attract attention for their potential in synthesis, catalysis and small
molecule activation. The coordination by N‐heterocyclic carbenes (NHCs) and cyclic …

Die Komplexierung von zwei Äquivalenten eines cyclischen (Alkyl)(amino) carbens (CAAC)
an Tetrabromdiboran führte unter nachfolgender Reduktion mit vier Äquivalenten …