New insights into perfluorinated sulfonic-acid ionomers

A Kusoglu, AZ Weber - Chemical reviews, 2017 - ACS Publications
In this comprehensive review, recent progress and developments on perfluorinated sulfonic-
acid (PFSA) membranes have been summarized on many key topics. Although quite well …

State of understanding of Nafion

KA Mauritz, RB Moore - Chemical reviews, 2004 - ACS Publications
Nafion ionomers were developed and are produced by the EI DuPont Company. These
materials are generated by copolymerization of a perfluorinated vinyl ether comonomer with …

Recent advances in perfluorinated ionomer membranes: structure, properties and applications

C Heitner-Wirguin - Journal of membrane Science, 1996 - Elsevier
This paper is a survey of the studies made in recent years on perfluorinated membranes,
structure properties and applications. The properties and structure of these membranes …

Ion activity coefficients in ion exchange polymers: applicability of Manning's counterion condensation theory

J Kamcev, DR Paul, BD Freeman - Macromolecules, 2015 - ACS Publications
Manning's counterion condensation theory, originally developed for polyelectrolyte
solutions, was used to predict ion activity coefficients in charged (ie, ion exchange) …

Proton conduction mechanisms at low degrees of hydration in sulfonic acid–based polymer electrolyte membranes

SJ Paddison - Annual Review of Materials Research, 2003 - annualreviews.org
▪ Abstract The need to operate polymer electrolyte membrane (PEM) fuel cells at
temperatures above 100° C, where the amount of water in the membrane is restricted, has …

Conductance of Nafion 117 membranes as a function of temperature and water content

M Cappadonia, JW Erning, SMS Niaki, U Stimming - Solid State Ionics, 1995 - Elsevier
The conductance of Nafion membranes was investigated by means of impedance
spectroscopy as a function of temperature and of sample treatment. In addition to other …

Effect of fixed charge group concentration on equilibrium ion sorption in ion exchange membranes

J Kamcev, DR Paul, BD Freeman - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
Despite their increasing importance in many energy and water purification applications, few
systematic studies of ion sorption in ion exchange membranes exist where fixed charge …

Polymer electrolyte membranes incorporated with nanometer-size particles of Pt and/or metal-oxides: experimental analysis of the self-humidification and suppression …

M Watanabe, H Uchida, M Emori - The Journal of Physical …, 1998 - ACS Publications
Self-humidification behaviors of polymer electrolyte membranes (PEMs) were clarified
experimentally in polymer electrolyte fuel cells (PEFCs) operated with dry H2 and O2. New …

A review on cold start of proton exchange membrane fuel cells

Z Wan, H Chang, S Shu, Y Wang, H Tang - Energies, 2014 - mdpi.com
Successful and rapid startup of proton exchange membrane fuel cells (PEMFCs) at
subfreezing temperatures (also called cold start) is of great importance for their …

Investigation of low-temperature proton transport in Nafion using direct current conductivity and differential scanning calorimetry

EL Thompson, TW Capehart, TJ Fuller… - Journal of the …, 2006 - iopscience.iop.org
The proton conductance of Nafion 117 was measured as a function of water content and
temperature and compared to changes in the phase state of water. Conductance was …