Exploiting chemistry and molecular systems for quantum information science

MR Wasielewski, MDE Forbes, NL Frank… - Nature Reviews …, 2020 - nature.com
The power of chemistry to prepare new molecules and materials has driven the quest for
new approaches to solve problems having global societal impact, such as in renewable …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K

J Liu, YC Chen, JL Liu, V Vieru, L Ungur… - Journal of the …, 2016 - ACS Publications
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …

Giant coercivity and high magnetic blocking temperatures for N23− radical-bridged dilanthanide complexes upon ligand dissociation

S Demir, MI Gonzalez, LE Darago, WJ Evans… - Nature …, 2017 - nature.com
Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …

Record quantum tunneling time in an air-stable exchange-bias dysprosium macrocycle

Z Zhu, S Paul, C Zhao, J Wu, X Ying… - Journal of the …, 2024 - ACS Publications
In recent years, dysprosium macrocycle single-molecule magnets (SMMs) have received
increasing attention due to their excellent air/thermal stability, strong magnetic anisotropy …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …