Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Nuclear resonance vibrational spectroscopy (NRVS; also known as nuclear inelastic
scattering, NIS) is a synchrotron-based method that reveals the full spectrum of vibrational …

The vibrational motions of a molecule in its equilibrium or during a chemical reaction provide
a wealth of information about its structure, stability, and reactivity. This information is hidden …

This paper investigates the interaction between five-coordinate ferric hemes with bound
axial imidazole ligands and nitric oxide (NO). The corresponding model complex,[Fe …

Because of HNO's emerging role as an important effector molecule in biology, there is great
current interest in the coordination chemistry of HNO and its deprotonated form, the nitroxyl …

Diatomic molecules attached to complexed iron or cobalt centres are important in many
biological processes. In natural systems, metallotetrapyrrole units carry respiratory gases or …

Nuclear inelastic scattering of 57Fe labeled [NiFe] hydrogenase is shown to give information
on different states of the enzyme. It was thus possible to detect and assign Fe–CO and Fe …

The synchrotron radiation technique of nuclear resonant inelastic X-ray scattering (NRIXS),
also known as nuclear resonance vibrational spectroscopy or nuclear inelastic scattering …

This paper presents oriented single-crystal Nuclear Resonance Vibrational Spectroscopy
(NRVS) data for the six-coordinate (6C) ferrous heme-nitrosyl model complex [57Fe …

This review summarizes our current understanding of the geometric and electronic
structures of ferrous and ferric heme–nitrosyls, which are of key importance for the biological …