The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …

This review comprehensively covers the coordination chemistry of elemental phosphorus
during the years 2011–2020. The main part is dedicated to the activation of white …

Conversion of C–H bonds to C–N bonds via C–H amination promises to streamline the
synthesis of nitrogen-containing compounds. Nitrogen-group transfer (NGT) from metal …

Determining the nature and extent of covalency of early actinide chemical bonding is a
fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and …

The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …

Bioinspired hydrogenation of N2 to ammonia at ambient conditions by stepwise nitrogen
protonation/reduction with metal complexes in solution has experienced remarkable …

A variety of transition metal–nitrido complexes (metallonitrenes) have been isolated and
studied in the context of modeling intermediates in biological nitrogen fixation by the …

In this Forum Article, we discuss the use of redox-active pincer-type ligands to enable
multielectron reactivity, specifically nitrene group transfer, at the electron-poor metals …

Nitrene transfer catalyzed by a d0zirconium (IV) complex with a redox-active ligand is
reported. The redox-active ligand, bis (2-isopropylamido-4-methoxyphenyl) amide ([NNNcat] …

Light-driven N2 cleavage into molecular nitrides is an attractive strategy for synthetic
nitrogen fixation. However, suitable platforms are rare. Furthermore, the development of …