Tuning the degradation activity and pathways of chlorinated organic pollutants over CeO 2 catalyst with acid sites: synergistic effect of Lewis and Brønsted acid sites
X Lv, S Cai, J Chen, D Yan, M Jiang, J Chen… - Catalysis Science & …, 2021 - pubs.rsc.org
Enhancing the surface acidity has been seen as an effective strategy to optimize the
performance of catalysts for the degradation of chlorinated volatile organic compounds …
performance of catalysts for the degradation of chlorinated volatile organic compounds …
Catalytic oxychlorination versus oxybromination for methane functionalization
The catalytic oxyhalogenation is an attractive route for the functionalization of methane in a
single step. This study investigates methane oxychlorination (MOC) and oxybromination …
single step. This study investigates methane oxychlorination (MOC) and oxybromination …
Lanthanide compounds as catalysts for the one-step synthesis of vinyl chloride from ethylene
The industrial manufacture of vinyl chloride relies on a two-step process involving CuCl 2-
catalyzed ethylene oxychlorination to ethylene dichloride followed by thermal cracking of the …
catalyzed ethylene oxychlorination to ethylene dichloride followed by thermal cracking of the …
Oxychlorination–dehydrochlorination chemistry on bifunctional ceria catalysts for intensified vinyl chloride production
Ceria catalyzes the one‐step production of the vinyl chloride monomer (VCM) from ethylene
with a high yield because of its bifunctional character: redox centers oxychlorinate ethylene …
with a high yield because of its bifunctional character: redox centers oxychlorinate ethylene …
Insights into the sintering resistance of RuO 2/TiO 2–SiO 2 in the Deacon process: role of SiO 2
Y Liu, S Li, X Lu, R Ma, Y Fu, S Wang… - Catalysis Science & …, 2021 - pubs.rsc.org
The sintering of RuO2 is the main reason for the deactivation of supported RuO2 catalysts in
the oxidation of HCl to Cl2 with O2 as the oxidant, ie, the Deacon process. Although …
the oxidation of HCl to Cl2 with O2 as the oxidant, ie, the Deacon process. Although …
Insight into the effects of calcination temperature on the structure and performance of RuO 2/TiO 2 in the Deacon process
S Li, B Xu, Y Wang, Y Liu, X Lu, R Ma, Y Fu… - Catalysis Science & …, 2022 - pubs.rsc.org
Rutile-type TiO2 supported RuO2 (RuO2/TiO2) catalysts show a remarkable low-
temperature activity and a long lifetime and have been industrially applied in the oxidation of …
temperature activity and a long lifetime and have been industrially applied in the oxidation of …
氯化氢氧化反应催化剂研究进展
石坚， 杨建明， 惠丰， 袁俊， 梅苏宁， 余秦伟， 张前… - 化工进展, 2019 - hgjz.cip.com.cn
大量副产氯化氢的资源化高效利用是涉氯行业亟需解决的共性难题. 氯化氢催化氧化循环制氯气
是一个低能耗, 可持续发展的有效途径, 而催化剂的设计与制备是该过程的核心 …
是一个低能耗, 可持续发展的有效途径, 而催化剂的设计与制备是该过程的核心 …
[HTML][HTML] 用于Deacon 反应的Ru 基催化剂的研究现状
黄雅琦， 刘佳慧， 朱百慧， 卢信清， 马睿， 朱伟东… - Material …, 2022 - hanspub.org
化工原料氯的大量使用以及氯原子在众多涉氯化工过程中的利用率很低, 导致副产氯化氢的产生
量显著增长, 制约该行业的发展. Deacon 反应是一个低能耗, 高效率, 环境友好可解决大量副产 …
量显著增长, 制约该行业的发展. Deacon 反应是一个低能耗, 高效率, 环境友好可解决大量副产 …
[PDF][PDF] 氯乙烯单体合成催化剂研究进展
鲍玉香， 马宏飞， 脱永笑， 祁艳颖， 冯翔， 杨朝合， 陈德 - 化工进展, 2021 - hgjz.cip.com.cn
氯乙烯(VCM) 是应用于高分子化工的重要单体, 可以通过乙烯法及乙炔法制得.
乙烯氧氯化生产VCM 过程中二氯乙烷(EDC) 的裂解生成VCM 通常需要高温 …
乙烯氧氯化生产VCM 过程中二氯乙烷(EDC) 的裂解生成VCM 通常需要高温 …
Progress on catalysts for catalytic oxidation of hydrogen chloride
J SHI, J YANG, F HUI, J YUAN, S MEI, Q YU… - Chemical Industry …, 2019 - hgjz.cip.com.cn
The efficient utilization of huge amount of hydrogen chloride byproduct is in urgent need for
chlorine-based chemical industry. Heterogeneous catalytic oxidation of HCl (so-called …
chlorine-based chemical industry. Heterogeneous catalytic oxidation of HCl (so-called …