Two types of chiral Brønsted acid catalysts have been shown to catalyze regio-and
enantioselective nitroso aldol synthesis between nitrosobenzene and achiral enamine. The …

The history of peptide chemistry in our group is described. It all started with the cyclic
undecapeptide cyclosporin, the immunosuppressive compound, which is commercialised as …

Stoichiometric asymmetric processes - Journal of the Chemical Society, Perkin Transactions
1 (RSC Publishing) DOI:10.1039/B009236N Royal Society of Chemistry View PDF VersionPrevious …

A model of proline as a “kinetic conglomerate” can rationalize both the nonlinear effect in
proline‐catalyzed aldol reactions observed in early studies and the linearity observed more …

Herein is disclosed an efficient catalytic enantioselective protonation of enol acetates by
means of a readily implementable transition-metal-free chemical process. By making use of …

Enantioenriched (S)-phosphoglutaminic acid derivatives with up to 72% ee were obtained in
the catalytic enantioselective Michael reaction of the achiral phosphoglycine synthon. The …

A brief overview is presented of the field of organocatalysis using chiral H‐bond donors,
chiral Brønsted acids, and chiral counter‐anions (Fig. 1). The role of TADDOLs (= α, α, α …

Efficient Synthesis of (À)-(R)-Muscone by Enantioselective Protonation Page 1 Efficient
Synthesis of (À)-(R)-Muscone by Enantioselective Protonation by Charles Fehr*, Jose¬ …

Optically active (S)-α-amino acids are prepared in 54− 95% ee (12 cases) by reaction of the
Schiff base acetate of glycine tert-butyl ester with B-alkyl-9-BBN derivatives in the presence …

The catalytic asymmetric epoxidation of α, β-unsaturated ketones by tert-butylhydroperoxide
(TBHP) has been well established using rare-earth metal amides RE [N (SiMe3) 2] 3 (RE …