A single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …

Protic pyrazoles (N-unsubstituted pyrazoles) have been versatile ligands in various fields,
such as materials chemistry and homogeneous catalysis, owing to their proton-responsive …

Cross‐coupling of nitriles and alcohols offers an environmentally friendly and atom‐
economical method for the synthesis of various valuable compounds. These compounds …

Herein we report efficient catalytic hydrosilylations of nitroarenes to form the corresponding
aromatic amines using a well-defined manganese (II)–NNO pincer complex with a low …

An oxygen-dependent ligand-controlled chemoselective synthesis of vinyl nitriles and E-
olefins by coupling a variety of alcohols and benzyl cyanides, catalyzed by a well …

Despite the limited success of copper-catalyzed alkylations,(NNS) CuCl proved to be an
effective catalyst for the sp3 C–H alkylation of fluorene with alcohols. Various primary …

Nickel (II) complex 1 was utilized as a sustainable catalyst for α-alkylation of arylacetonitriles
with challenging secondary alcohols. Arylacetonitriles with a wide range of functional groups …

In the present work, several manganese (I) complexes of chelating heteroditopic ligands
Mn1–3, featuring ImNHC (imidazol‐2‐ylidene) connected to a 1, 2, 3‐triazole‐N or tzNHC …

A regioselective [3+ 2] cycloaddition (32CA) reaction to synthesize unsymmetric spiro-
barbituric pyrazolines containing a chromone or phenolic pyrazole moiety was achieved …

A catalytic strategy employing a Ru–Fe bimetallic heterogeneous catalyst is presented for α-
olefination and α-alkylation of nitriles using secondary alcohols. Currently, catalysis for this …