On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds
While β-diketiminate (BDI or 'nacnac') ligands have been widely adopted to stabilize a wide
range of metal ions in multiple oxidation states and coordination numbers, in several …
range of metal ions in multiple oxidation states and coordination numbers, in several …
Closed-shell and open-shell square-planar iridium nitrido complexes
MG Scheibel, B Askevold, FW Heinemann… - Nature Chemistry, 2012 - nature.com
Coupling reactions of nitrogen atoms represent elementary steps to many important
heterogeneously catalysed reactions, such as the Haber–Bosch process or the selective …
heterogeneously catalysed reactions, such as the Haber–Bosch process or the selective …
1, 4-Bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadienes as strong salt-free reductants for generating low-valent early transition metals with electron-donating ligands
T Saito, H Nishiyama, H Tanahashi… - Journal of the …, 2014 - ACS Publications
Electron-rich organosilicon compounds, such as 1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-
cyclohexadiene (2a), 2, 5-dimethyl-1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadiene …
cyclohexadiene (2a), 2, 5-dimethyl-1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadiene …
Synthesis and Characterization of an f-Block Terminal Parent Imido [U NH] Complex: A Masked Uranium (IV) Nitride
DM King, J McMaster, F Tuna… - Journal of the …, 2014 - ACS Publications
Deprotonation of [U (TrenTIPS)(NH2)](1)[TrenTIPS= N (CH2CH2NSiPri3) 3] with
organoalkali metal reagents MR (M= Li, R= But; M= Na–Cs, R= CH2C6H5) afforded the …
organoalkali metal reagents MR (M= Li, R= But; M= Na–Cs, R= CH2C6H5) afforded the …
Homolytic N–H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species
MG Scheibel, J Abbenseth, M Kinauer… - Inorganic …, 2015 - ACS Publications
The redox series [Ir n (NH x)(PNP)](n= II–IV, x= 3–0; PNP= N (CHCHP t Bu2) 2) was
examined with respect to electron, proton, and hydrogen atom transfer steps. The …
examined with respect to electron, proton, and hydrogen atom transfer steps. The …
Direct incorporation of dinitrogen into an aliphatic C–H bond
SJ Xie, RK Wu, YF Huang, HL Chen… - Journal of the …, 2023 - ACS Publications
The activation of dinitrogen (N2) and direct incorporation of its N atom into C–H bonds to
create aliphatic C–N compounds remains unresolved. Incompatible conditions between …
create aliphatic C–N compounds remains unresolved. Incompatible conditions between …
Actinide Pnictinidene Chemistry: A Terminal Thorium Parent‐Arsinidene Complex Stabilised by a Super‐Bulky Triamidoamine Ligand
We report the direct synthesis of the terminal pnictidenes [An (TrenTCHS)(PnH)][M (2, 2, 2‐
cryptand)](TrenTCHS={N (CH2CH2NSiCy3) 3} 3−; An/Pn/M= Th/P/Na 5, Th/As/K 6, U/P/Na …
cryptand)](TrenTCHS={N (CH2CH2NSiCy3) 3} 3−; An/Pn/M= Th/P/Na 5, Th/As/K 6, U/P/Na …
C–H bond addition across a transient uranium–nitrido moiety and formation of a parent uranium imido complex
KC Mullane, H Ryu, T Cheisson, LN Grant… - Journal of the …, 2018 - ACS Publications
Uranium complexes in the+ 3 and+ 4 oxidation states were prepared using the anionic PN–
(PN–=(N-(2-(diisopropylphosphino)-4-methylphenyl)-2, 4, 6-trimethylanilide) ligand …
(PN–=(N-(2-(diisopropylphosphino)-4-methylphenyl)-2, 4, 6-trimethylanilide) ligand …
Mononuclear three-coordinate magnesium complexes of a highly sterically encumbered β-diketiminate ligand
M Arrowsmith, B Maitland, G Kociok-Köhn… - Inorganic …, 2014 - ACS Publications
The highly sterically encumbered chelating β-diketiminate ligand,[HC {C (Me) N (2, 6-
CHPh2-4-MeC6H2)} 2]−, ArL–, has been used to prepare a series of heteroleptic three …
CHPh2-4-MeC6H2)} 2]−, ArL–, has been used to prepare a series of heteroleptic three …
An iridium (III/IV/V) redox series featuring a terminal imido complex with triplet ground state
M Kinauer, M Diefenbach, H Bamberger… - Chemical …, 2018 - pubs.rsc.org
The iridium (III/IV/V) imido redox series [Ir (NtBu){N (CHCHPtBu2) 2}] 0/+/2+ was synthesized
and examined spectroscopically, magnetically, crystallographically and computationally …
and examined spectroscopically, magnetically, crystallographically and computationally …