Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies
SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …
from being a sub-discipline of molecular magnetism to an established field of research in its …
Large magnetic anisotropy in mononuclear metal complexes
S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …
theoretical approaches used to rationalize their magnetic properties. Electronic structure …
Molcas 8: New capabilities for multiconfigurational quantum chemical calculations across the periodic table
In this report, we summarize and describe the recent unique updates and additions to the
Molcas quantum chemistry program suite as contained in release version 8. These updates …
Molcas quantum chemistry program suite as contained in release version 8. These updates …
Uncommon lanthanide ions in purely 4f Single Molecule Magnets
F Pointillart, O Cador, B Le Guennic… - Coordination Chemistry …, 2017 - Elsevier
Since the 1990s and the discovery of the first Single Molecule Magnets (SMMs), chemists
and physicists have been working in concert to elaborate such molecular systems and …
and physicists have been working in concert to elaborate such molecular systems and …
A journey in lanthanide coordination chemistry: from evaporable dimers to magnetic materials and luminescent devices
Conspectus Lanthanide ions are prime ingredients for the design of compounds, materials,
and devices with unique magnetic and optical properties. Accordingly, coordination …
and devices with unique magnetic and optical properties. Accordingly, coordination …
Magnetic memory in an isotopically enriched and magnetically isolated mononuclear dysprosium complex
F Pointillart, K Bernot, S Golhen… - Angewandte …, 2015 - Wiley Online Library
The influence of nuclear spin on the magnetic hysteresis of a single‐molecule is evidenced.
Isotopically enriched DyIII complexes are synthesized and an isotopic dependence of their …
Isotopically enriched DyIII complexes are synthesized and an isotopic dependence of their …
Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …
(SMMs), as any future potential application in this class of molecules is directly correlated to …
Influence of Pyrazolate vs N-Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes
KR Meihaus, SG Minasian, WW Lukens Jr… - Journal of the …, 2014 - ACS Publications
Two isostructural series of trigonal prismatic complexes, M (BpMe) 3 and M (BcMe) 3 (M= Y,
Tb, Dy, Ho, Er, U;[BpMe]−= dihydrobis (methypyrazolyl) borate;[BcMe]−= dihydrobis …
Tb, Dy, Ho, Er, U;[BpMe]−= dihydrobis (methypyrazolyl) borate;[BcMe]−= dihydrobis …
Water-driven reversible switching of single-ion magnetism and proton conduction in a dysprosium sulfonate
We report the design and synthesis of a 1D Dy (III) coordination polymer, comprised of
sulfonate functionalised ligand 8-hydroxyquinoline-5-sulfonic acid (H2SQ) and Dy3+ ions …
sulfonate functionalised ligand 8-hydroxyquinoline-5-sulfonic acid (H2SQ) and Dy3+ ions …
Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy 4 clusters
WM Wang, XM Kang, HY Shen, ZL Wu… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Three Dy4 clusters,[Dy4 (tmhd) 8 (L) 2 (CH3OH) 2]· CH3OH (1),[Dy4 (hfac) 8 (L) 2 (DMF) 2]·
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …