Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …

Spin dynamics in single-molecule magnets and molecular qubits

D Aravena, E Ruiz - Dalton Transactions, 2020 - pubs.rsc.org
Over recent decades, much effort has been made to lengthen spin relaxation/decoherence
times of single-molecule magnets and molecular qubits by following different chemical …

Lanthanide Double Perovskite Nanocrystals with Emissions Covering the UV‐C to NIR Spectral Range

P Saghy, AM Brown, C Chu, LC Dube… - Advanced Optical …, 2023 - Wiley Online Library
Lead halide perovskite nanocrystals (NCs) have recently drawn considerable attention in
the fields of materials science and nanotechnology. However, a major drawback of these …

Discovery and evolution of polyoxopalladates

P Yang, U Kortz - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Noble metal catalysts, in particular palladium-containing materials, are of prime
commercial interest, because of their role as oxidation catalysts in automobile emission …

Binary Heterogroup-Templated Scaffolds of Polyoxopalladates as Precatalysts for Plasma-Assisted Ammonia Synthesis

Y Zhao, K Li, J Du, CQ Chen, S Chen… - ACS Applied Materials & …, 2023 - ACS Publications
In addition to improving the synthetic efficiency, the template method can do a lot more in the
chemistry of polyoxopalladates (POPs), such as the establishment of novel metal-oxo …

Polyoxometalates: tailoring metal oxides in molecular dimension toward energy applications

L Zhang, Z Chen - International Journal of Energy Research, 2020 - Wiley Online Library
Polyoxometalates could be viewed as the molecular counterpart of the metal oxides, which
are essential ingredients for various energy conversion and storage applications. In this …

Exploiting clock transitions for the chemical design of resilient molecular spin qubits

S Giménez-Santamarina, S Cardona-Serra… - Chemical …, 2020 - pubs.rsc.org
Molecular spin qubits are chemical nanoobjects with promising applications that are so far
hampered by the rapid loss of quantum information, a process known as decoherence. A …

Exploring the high-temperature frontier in molecular nanomagnets: from lanthanides to actinides

L Escalera-Moreno, JJ Baldoví, A Gaita-Ariño… - Inorganic …, 2019 - ACS Publications
Molecular nanomagnets based on mononuclear metal complexes, also known as single-ion
magnets (SIMs), are crossing challenging boundaries in molecular magnetism. From an …

Selective Lanthanide Distribution within a Comprehensive Series of Heterometallic [LnPr] Complexes

D Aguila, V Velasco, LA Barrios… - Inorganic …, 2018 - ACS Publications
The preparation of heterometallic, lanthanide-only complexes is an extremely difficult
synthetic challenge. By a ligand-based strategy, a complete isostructural series of dinuclear …

Host–Guest Chemistry in Discrete Polyoxo-12-Palladate(II) Cubes [MO8Pd12L8]n (M = ScIII, CoII, CuII, L = AsO43 –; M = CdII, HgII, L = PhAsO32–) …

P Yang, ME Mahmoud, Y Xiang, Z Lin, X Ma… - Inorganic …, 2022 - ACS Publications
A family of five host–guest assemblies comprising different metal ions inside a cuboid 12-
palladium-oxo cage,[MO8Pd12L8] n−(MPd 12 L 8, M= ScIII, CoII, CuII, L= AsO43–; M= CdII …