Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development
RO Pankov, DO Prima, VP Ananikov - Coordination Chemistry Reviews, 2024 - Elsevier
In the field of catalytic chemistry, metal complexes containing N-heterocyclic carbenes
(NHCs) have gained significant attention due to their versatile nature and wide range of …
(NHCs) have gained significant attention due to their versatile nature and wide range of …
A general protocol for the synthesis of Pt-NHC (NHC= N-heterocyclic carbene) hydrosilylation catalysts
BP Maliszewski, NV Tzouras, SG Guillet, M Saab… - Dalton …, 2020 - pubs.rsc.org
A general, user-friendly synthetic route to [Pt (NHC)(L) Cl2] and [Pt (NHC)(dvtms)](L= DMS,
Py; DMS= dimethyl sulfide, dvtms= divinyltetramethylsiloxane, Py= pyridine) complexes has …
Py; DMS= dimethyl sulfide, dvtms= divinyltetramethylsiloxane, Py= pyridine) complexes has …
Transfer hydrogenation from glycerol: Activity and recyclability of iridium and ruthenium sulfonate-functionalized n-heterocyclic carbene catalysts
Three ruthenium (II) and two iridium (III) N-heterocyclic carbene (NHC) complexes
functionalized with sulfonates are compared with respect to their activity and selectivity for …
functionalized with sulfonates are compared with respect to their activity and selectivity for …
Highly selective hydrosilylation of olefins and acetylenes by platinum (0) complexes bearing bulky N-heterocyclic carbene ligands
P Żak, M Bołt, M Kubicki, C Pietraszuk - Dalton transactions, 2018 - pubs.rsc.org
Platinum complexes bearing bulky N-heterocyclic carbene (NHC) ligands, ie,[Pt
(IPr*)(dvtms)](where, IPr*= 1, 3-bis {2, 6-bis (diphenylmethyl)-4-methylphenyl} imidazol-2 …
(IPr*)(dvtms)](where, IPr*= 1, 3-bis {2, 6-bis (diphenylmethyl)-4-methylphenyl} imidazol-2 …
Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts
S Shimada - Perspectives of Hydrosilylation Reactions, 2023 - Springer
This chapter summarizes recent advances of group 10 transition metal hydrosilylation
catalysts from 2015 onward. Since the discovery of Speier's catalyst in 1957, homogeneous …
catalysts from 2015 onward. Since the discovery of Speier's catalyst in 1957, homogeneous …
A family of rhodium (i) NHC chelates featuring O-containing tethers for catalytic tandem alkene isomerization–hydrosilylation
R Srivastava, M Jakoobi, C Thieuleux… - Dalton …, 2021 - pubs.rsc.org
The rhodium complex Rh (HL)(COD) Cl, 1, L being a functionalized N-heterocyclic carbene
(NHC) ligand with an oxygen-containing pendant arm, has been used as the entry point to …
(NHC) ligand with an oxygen-containing pendant arm, has been used as the entry point to …
Construction of Six‐Membered Silacyclic Skeletons via Platinum‐Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes
PW Long, XF Bai, F Ye, L Li, Z Xu… - Advanced Synthesis …, 2018 - Wiley Online Library
Catalytic silicon‐carbon or silicon‐heteroatom bond‐forming hydrosilylation has become
increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein …
increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein …
Synthesis and characterization of Markó-type (NHC) Pt (dvtms) complexes and their evaluation in the hydrosilylation reaction of alkenes
MJ Sauer, LF Richter, J Offorjindu, RM Reich… - Journal of …, 2024 - Elsevier
A series of Markó-type complexes of the structure (NHC) Pt (dvtms) were prepared (dvtms=
1, 1, 3, 3-tetramethyl-1, 3-divinyldisiloxane, NHC= N-heterocyclic carbene, Im= imidazole …
1, 1, 3, 3-tetramethyl-1, 3-divinyldisiloxane, NHC= N-heterocyclic carbene, Im= imidazole …
Platinum Complexes Bearing Bulky N‐Heterocyclic Carbene Ligands as Efficient Catalysts for the Fully Selective Dimerization of Terminal Alkynes
P Żak, M Bołt, J Lorkowski, M Kubicki… - …, 2017 - Wiley Online Library
New platinum (0) complexes of the general formula [(NHC) Pt (dvtms)](dvtms= 1, 3‐
divinyltetramethyldisiloxane) containing bulky N‐heterocyclic carbene (NHC) ligands were …
divinyltetramethyldisiloxane) containing bulky N‐heterocyclic carbene (NHC) ligands were …
Platinum‐Catalyzed Multicomponent Alcoholysis/Hydrosilylation and Bis‐hydrosilylation of Alkynes with Dihydrosilanes
JX Xu, MY Chen, ZJ Zheng, J Cao, Z Xu… - …, 2017 - Wiley Online Library
A new method for the hydrosilylation of alkynes controlled by a platinum catalyst with a
monophosphine ligand (called TBSO‐MOP) was explored. The platinum‐catalyzed …
monophosphine ligand (called TBSO‐MOP) was explored. The platinum‐catalyzed …