Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity
TW van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …
reactions. Metal-support interactions in these nanomaterials can have a substantial …
Non-carbon-supported single-atom site catalysts for electrocatalysis
Single-atom site catalysts (SACs) have received considerable attention for electrocatalytic
applications, owing to their maximum atom-utilization efficiency, well-identified active …
applications, owing to their maximum atom-utilization efficiency, well-identified active …
Regulating local electron density of iron single sites by introducing nitrogen vacancies for efficient photo‐fenton process
L Su, P Wang, X Ma, J Wang, S Zhan - Angewandte Chemie, 2021 - Wiley Online Library
The activity of heterogeneous photocatalytic H2O2 activation in Fenton‐like processes is
closely related to the local electron density of reaction centre atoms. However, the …
closely related to the local electron density of reaction centre atoms. However, the …
Modulating electron density of vacancy site by single Au atom for effective CO2 photoreduction
Y Cao, L Guo, M Dan, DE Doronkin, C Han… - Nature …, 2021 - nature.com
The surface electron density significantly affects the photocatalytic efficiency, especially the
photocatalytic CO2 reduction reaction, which involves multi-electron participation in the …
photocatalytic CO2 reduction reaction, which involves multi-electron participation in the …
Reaction-induced strong metal–support interactions between metals and inert boron nitride nanosheets
Encapsulation of metal nanocatalysts by support-derived materials is well known as a
classical strong metal–support interaction (SMSI) effect that occurs almost exclusively with …
classical strong metal–support interaction (SMSI) effect that occurs almost exclusively with …
Electronic structure reconfiguration of nickel–cobalt layered double hydroxide nanoflakes via engineered heteroatom and oxygen-vacancies defect for efficient …
K Chen, YH Cao, S Yadav, GC Kim, Z Han… - Chemical Engineering …, 2023 - Elsevier
The development of earth-abundant and high-efficiency bifunctional electrocatalysts is
extremely desirable for electrochemical water splitting, but there are some critical challenges …
extremely desirable for electrochemical water splitting, but there are some critical challenges …
Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution
Metal–support interaction is of great significance for catalysis as it can induce charge
transfer between metal and support, tame electronic structure of supported metals, impact …
transfer between metal and support, tame electronic structure of supported metals, impact …
Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles
Abstract Platinum nanoparticles (Pt NPs) are one of the most efficient cocatalysts in
photocatalysis, and their size determines the activity and the selectivity of the catalytic …
photocatalysis, and their size determines the activity and the selectivity of the catalytic …
Insights into the use of Te–O pairs as active centers of carbon nanosheets for efficient electrochemical oxygen reduction
Previous theoretical calculations have predicted that the incorporation of tellurium (Te) into
carbon materials can significantly enhance their catalytic activity. Nevertheless, the …
carbon materials can significantly enhance their catalytic activity. Nevertheless, the …
Constructing atomic surface concaves on Bi5O7Br nanotube for efficient photocatalytic CO2 reduction
The development of advanced photocatalysts for CO 2 reduction (CO 2 R) has attracted
intensive interest but is severely plagued by the intrinsically narrow photo-responsive range …
intensive interest but is severely plagued by the intrinsically narrow photo-responsive range …