Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Pd metal catalysts for cross-couplings and related reactions in the 21st century: a critical review

A Biffis, P Centomo, A Del Zotto, M Zecca - Chemical Reviews, 2018 - ACS Publications
Cross-couplings and related reactions are a class of highly efficient synthetic protocols that
are generally promoted by molecular Pd species as catalysts. However, catalysts based on …

Transition metal nanoparticles as nanocatalysts for Suzuki, Heck and Sonogashira cross-coupling reactions

M Ashraf, MS Ahmad, Y Inomata, N Ullah… - Coordination Chemistry …, 2023 - Elsevier
Transition metal (TM) catalyzed cross-coupling reactions are the utmost versatile and
reliable methods for the production of many industrially important fine chemicals. The …

The Suzuki-Miyaura reaction after the Nobel prize

IP Beletskaya, F Alonso, V Tyurin - Coordination Chemistry Reviews, 2019 - Elsevier
Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …

The recent development of efficient Earth-abundant transition-metal nanocatalysts

D Wang, D Astruc - Chemical Society Reviews, 2017 - pubs.rsc.org
Whereas noble metal compounds have long been central in catalysis, Earth-abundant metal-
based catalysts have in the same time remained undeveloped. Yet the efficacy of Earth …

Solvent effects in palladium catalysed cross-coupling reactions

J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019 - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

A retrospective-prospective review of Suzuki–Miyaura reaction: From cross-coupling reaction to pharmaceutical industry applications

M Farhang, AR Akbarzadeh, M Rabbani, AM Ghadiri - Polyhedron, 2022 - Elsevier
Carbon-carbon coupling is the most important reaction in chemical, academia, and industrial
scales. The Suzuki-Miyaura coupling is a cross-coupling reaction in which the coupling …

Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching,“Cocktails” of catalysts and dynamic systems

DB Eremin, VP Ananikov - Coordination Chemistry Reviews, 2017 - Elsevier
In the present review, we consider the transformations of molecular catalysts, leaching,
aggregation and various interconversions of metal complexes, clusters and nanoparticles …

Combinations of aminocatalysts and metal catalysts: a powerful cooperative approach in selective organic synthesis

S Afewerki, A Cordova - Chemical reviews, 2016 - ACS Publications
The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

Nano-magnetite (Fe 3 O 4) as a support for recyclable catalysts in the development of sustainable methodologies

MB Gawande, PS Branco, RS Varma - Chemical Society Reviews, 2013 - pubs.rsc.org
Surface functionalization of nano-magnetic nanoparticles is a well-designed way to bridge
the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic …