[HTML][HTML] A review of automated and data-driven approaches for pathway determination and reaction monitoring in complex chemical systems

A Puliyanda, K Srinivasan, K Sivaramakrishnan… - Digital Chemical …, 2022 - Elsevier
In this work, we review the state of the art on approaches for the determination of reaction
networks and the real-time monitoring of reactions in complex chemical systems consisting …

Variant and invariant states for chemical reaction systems

D Rodrigues, S Srinivasan, J Billeter… - Computers & Chemical …, 2015 - Elsevier
Abstract Models of chemical reaction systems can be quite complex as they typically include
information regarding the reactions, the inlet and outlet flows, the transfer of species …

Incremental identification of reaction systems—A comparison between rate-based and extent-based approaches

N Bhatt, N Kerimoglu, M Amrhein, W Marquardt… - Chemical engineering …, 2012 - Elsevier
Two incremental approaches are available in the literature to identify the kinetics of either
homogeneous or fluid–fluid reaction systems from transient concentration measurements …

Incremental identification of reaction and mass–transfer kinetics using the concept of extents

N Bhatt, M Amrhein, D Bonvin - Industrial & engineering chemistry …, 2011 - ACS Publications
This paper proposes a variation of the incremental approach to identify reaction and mass-
transfer kinetics from concentration measurements for both homogeneous and gas–liquid …

Rapid Kinetic Modeling of Reaction Systems from Spectroscopic Data in Flow Reactors

M Veeramani, SS Doss, S Narasimhan… - Chemical Engineering …, 2024 - Elsevier
Continuous flow micro-reactors have been increasingly used for kinetic studies as they
possess superior heat and mass transfer properties and consume fewer reagents than …

A perturbed port-Hamiltonian approach for the stabilization of homogeneous reaction systems via the control of vessel extents

TS Nguyen, CK Tan, NH Hoang, MA Hussain… - Computers & Chemical …, 2021 - Elsevier
The paper proposes a tracking-error passivity-based control scheme for the asymptotic
stabilization of homogeneous reaction systems. The approach uses the concept of vessel …

Modeling of reactive batch distillation processes for control

A Marquez-Ruiz, CS Méndez-Blanco… - Computers & Chemical …, 2019 - Elsevier
Reactive batch distillation (RBD) is a preferred process intensification technology to carry
out equilibrium-limited reactions. It is a multicomponent, multiphase system. Appropriate …

Revisiting the concept of extents for chemical reaction systems using an enthalpy balance

NH Hoang, D Rodrigues, D Bonvin - Computers & Chemical Engineering, 2020 - Elsevier
For the investigation of complex reaction systems, it has been proposed to decouple the
various rate processes using a linear time-invariant transformation that is constructed from …

Microfluidics-based determination of diffusion coefficient for gas-liquid reaction system with hydrogen peroxide

J Qiu, B Bao, S Zhao, X Lu - Chemical Engineering Science, 2021 - Elsevier
In this work, we present a fluorescence-based microfluidic approach to study the transport
characteristics in gas–liquid reaction system with hydrogen peroxide (H 2 O 2). A system of …

Quo Vadis advanced chemical process control

S Dubljevic - The Canadian Journal of Chemical Engineering, 2022 - Wiley Online Library
The current state of advanced chemical and materials process control can be determined by
reviewing the past contributions and contemporary developments in the field. The past two …