Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

A strong underwater adhesive that totally cured in water

Y Yan, J Huang, X Qiu, D Zhuang, H Liu… - Chemical Engineering …, 2022 - Elsevier
Underwater adhesives have drawn enormous interests for biomedical and engineering
applications. In this work, a strong underwater adhesive is developed by addition reaction …

Modeling and theoretical development in controlled radical polymerization

E Mastan, X Li, S Zhu - Progress in Polymer Science, 2015 - Elsevier
Controlled radical polymerization (CRP) systems have gained increasing interests for the
past two decades. Numerous publications may be found in the literature reporting …

Model-based design of the polymer microstructure: bridging the gap between polymer chemistry and engineering

DR D'hooge, PHM Van Steenberge, P Derboven… - Polymer …, 2015 - pubs.rsc.org
The performance of polymeric materials depends strongly on the control over the polymer
microstructure during the synthesis step. In this review, attention is paid to the potential of …

Scavenging of organic C-centered radicals by nitroxides

EG Bagryanskaya, SRA Marque - Chemical reviews, 2014 - ACS Publications
1. INTRODUCTION For more than two decades, from the 1960s to the mid-1980s,
fundamental research in radical chemistry aroused tremedeous interest in the physical …

State‐of‐the‐art and progress in method of moments for the model‐based reversible‐deactivation radical polymerization

YN Zhou, ZH Luo - Macromolecular Reaction Engineering, 2016 - Wiley Online Library
Reversible‐deactivation radical polymerization (RDRP) techniques have received lots of
interest for the past 20 years, not only owing to their simple, mild reaction conditions and …

Virtual Free-Radical Polymerization of Vinyl Monomers in View of Digital Twins

EF Sheka - Polymers, 2023 - mdpi.com
The first case of virtual polymerization based on the concept of digital twins (DTs) is
presented. The free-radical polymerization of vinyl monomers is considered to be a chain …

Nitroxide‐mediated polymerization of methacrylic esters: insights and solutions to a long‐standing problem

E Guégain, Y Guillaneuf… - Macromolecular rapid …, 2015 - Wiley Online Library
Nitroxide‐mediated polymerization (NMP) is one of the most powerful reversible
deactivation radical polymerization techniques and has incredibly gained in maturity and …