Synthesis, structures and applications of electron-rich polyoxometalates

NI Gumerova, A Rompel - Nature Reviews Chemistry, 2018 - nature.com
Ever since the discovery and development of polyoxometalates (POMs), it has been known
that they can exist in electron-rich reduced forms of different archetypes, structural …

Proton conduction in ionic crystals based on polyoxometalates

N Ogiwara, T Iwano, T Ito, S Uchida - Coordination Chemistry Reviews, 2022 - Elsevier
Polyoxometalates (POMs) have attracted considerable attention as an important class of
proton-conductive materials since POMs can efficiently transport protons due to their small …

Polyoxometalates-functionalized electrodes for (photo) electrocatalytic applications: Recent advances and prospects

B Fabre, C Falaise, E Cadot - ACS Catalysis, 2022 - ACS Publications
This review is intended to provide an up-to-date and comprehensive description of recent
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …

Magnetic interactions in molecules and highly correlated materials: physical content, analytical derivation, and rigorous extraction of magnetic Hamiltonians

JP Malrieu, R Caballol, CJ Calzado, C De Graaf… - Chemical …, 2014 - ACS Publications
Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …

Effective storage of electrons in water by the formation of highly reduced polyoxometalate clusters

JJ Chen, L Vilà-Nadal, A Solé-Daura… - Journal of the …, 2022 - ACS Publications
Aqueous solutions of polyoxometalates (POMs) have been shown to have potential as high-
capacity energy storage materials due to their potential for multi-electron redox processes …

Lanthanoid Single-Ion Magnets Based on Polyoxometalates with a 5-fold Symmetry: The Series [LnP5W30O110]12– (Ln3+ = Tb, Dy, Ho, Er, Tm, and Yb)

S Cardona-Serra, JM Clemente-Juan… - Journal of the …, 2012 - ACS Publications
A robust, stable and processable family of mononuclear lanthanoid complexes based on
polyoxometalates (POMs) that exhibit single-molecule magnetic behavior is described here …

Ab initio and DFT modelling of complex materials: towards the understanding of electronic and magnetic properties of polyoxometalates

JM Poblet, X López, C Bo - Chemical Society Reviews, 2003 - pubs.rsc.org
In this review we summarise the quantum chemistry studies carried out by several groups
over the last ten years on polyoxometalates, or polyoxoanions. This is an immense family of …

Effect of on-site Coulomb repulsion term on the band-gap states of the reduced rutile (110) surface

CJ Calzado, NC Hernández, JF Sanz - Physical Review B—Condensed Matter …, 2008 - APS
We present a study concerning the effect of the on site dd Coulomb interaction energy U on
the band-gap states of nonstoichiometric rutile (110) Ti O 2 surface. As well known, the …

Polyoxometalate-based layered structures for charge transport control in molecular devices

AM Douvas, E Makarona, N Glezos, P Argitis… - ACS …, 2008 - ACS Publications
Hybrid organic–inorganic films consisted of molecular layers of a Keggin-structure
polyoxometalate (POM: 12-tungstophosphoric acid, H3PW12O40) and 1, 12 …

On the origin of alternating bond distortions and the emergence of chirality in polyoxometalate anions

L Yan, X López, JJ Carbó, R Sniatynsky… - Journal of the …, 2008 - ACS Publications
Alternating short and long bond length (ABL) distortions observed within the ring structures
of molecular metal oxide anions or polyoxometalates (POMs) are reminiscent of the …