[HTML][HTML] Artificial molecular machines

S Erbas-Cakmak, DA Leigh, CT McTernan… - Chemical …, 2015 - ACS Publications
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

Controlling motion at the nanoscale: rise of the molecular machines

JM Abendroth, OS Bushuyev, PS Weiss, CJ Barrett - ACS nano, 2015 - ACS Publications
As our understanding and control of intra-and intermolecular interactions evolve, ever more
complex molecular systems are synthesized and assembled that are capable of performing …

Nonconjugated hydrocarbons as rigid‐linear motifs: Isosteres for material sciences and bioorganic and medicinal chemistry

GM Locke, SSR Bernhard… - Chemistry–A European …, 2019 - Wiley Online Library
Abstract Nonconjugated hydrocarbons, like bicyclo [1.1. 1] pentane, bicyclo [2.2. 2] octane,
triptycene, and cubane are a unique class of rigid linkers. Due to their similarity in size and …

Wholly synthetic molecular machines

C Cheng, JF Stoddart - ChemPhysChem, 2016 - Wiley Online Library
The past quarter of a century has witnessed an increasing engagement on the part of
physicists and chemists in the design and synthesis of molecular machines de novo. This …

Understanding surface and interfacial chemistry in functional nanomaterials via solid‐state NMR

A Marchetti, J Chen, Z Pang, S Li, D Ling… - Advanced …, 2017 - Wiley Online Library
Surface and interfacial chemistry is of fundamental importance in functional nanomaterials
applied in catalysis, energy storage and conversion, medicine, and other nanotechnologies …

Halogen bonding as a supramolecular dynamics catalyst

PMJ Szell, S Zablotny, DL Bryce - Nature communications, 2019 - nature.com
Dynamic processes have many implications in functional molecules, including catalysts,
enzymes, host-guest complexes, and molecular machines. Here, we demonstrate via …

Gyroscopes and the chemical literature, 2002–2020: approaches to a nascent family of molecular devices

A Ehnbom, JA Gladysz - Chemical Reviews, 2021 - ACS Publications
Research directed toward the goal of molecular gyroscopes since the coverage of a
previous review (2002) is described. Such species are a subclass of molecular rotors, which …

Time-dependent solid-state molecular motion and colour tuning of host-guest systems by organic solvents

YD Yang, X Ji, ZH Lu, J Yang, C Gao, H Zhang… - Nature …, 2020 - nature.com
Host-guest complex solid state molecular motion is a critical but underexplored
phenomenon. In principle, it can be used to control molecular machines that function in the …

Anisotropic thermal expansion as the source of macroscopic and molecular scale motion in phosphorescent amphidynamic crystals

M Jin, S Yamamoto, T Seki, H Ito… - Angewandte Chemie …, 2019 - Wiley Online Library
Herein we report a crystalline molecular rotor with rotationally modulated triplet emission
that displays macroscopic dynamics in the form of crystal moving and/or jumping, also …

Rotors, motors, and machines inside metal–organic frameworks

P Martinez-Bulit, AJ Stirk, SJ Loeb - Trends in Chemistry, 2019 - cell.com
Chemists have learned how to create molecules that mimic the rudimentary motions
exhibited at the macroscopic level by some of the components of modern machinery. Almost …