Direct detection of the open-shell singlet phenyloxenium ion: an atom-centered diradical reacts as an electrophile
A new photoprecursor to the phenyloxenium ion, 4-methoxyphenoxypyridinium
tetrafluoroborate, was investigated using trapping studies, product analysis, computational …
tetrafluoroborate, was investigated using trapping studies, product analysis, computational …
Quantum chemistry of the excited state: recent trends in methods developments and applications
M Navarrete-Miguel, J Segarra-Martí… - 2018 - books.rsc.org
Advances (2016–2017) in Quantum Chemistry of the Excited State (QCEX) are presented in
this book chapter focusing firstly on developments of methodology and excited-state reaction …
this book chapter focusing firstly on developments of methodology and excited-state reaction …
Stoichiometric nitroxyl photorelease using the (6-hydroxy-2-naphthalenyl) methyl phototrigger
Y Zhou, RB Cink, AJ Seed, MC Simpson… - Organic …, 2019 - ACS Publications
The design and synthesis of a photoactivatable HNO donor incorporating the (6-
hydroxynaphthalen-2-yl) methyl (6, 2-HNM) photocage coupled to the …
hydroxynaphthalen-2-yl) methyl (6, 2-HNM) photocage coupled to the …
Direct observation of photoinduced ultrafast generation of singlet and triplet quinone methides in aqueous solutions and insight into the roles of acidic and basic sites …
J Ma, X Zhang, N Basarić… - Journal of the American …, 2017 - ACS Publications
Femtosecond time-resolved transient absorption spectroscopy experiments and density
functional theory computations were done for a mechanistic investigation of 3-(1 …
functional theory computations were done for a mechanistic investigation of 3-(1 …
Time-Resolved Spectroscopic Study of N,N-Di(4-bromo)nitrenium Ions in Selected Solutions
Nitrenium ions are important reactive intermediates in chemistry and biology. In this work,
femtosecond and nanosecond transient absorption (fs-TA and ns-TA) along with …
femtosecond and nanosecond transient absorption (fs-TA and ns-TA) along with …
Time-Resolved Spectroscopic Study of N,N–Di(4–bromo)nitrenium Ions in Acidic Aqueous Solution
Nitrenium ions are common reactive intermediates with high activities towards some
biological nucleophiles. In this paper, we employed femtosecond transient absorption (fs …
biological nucleophiles. In this paper, we employed femtosecond transient absorption (fs …
Time-resolved spectroscopic observation of diphenylnitrenium ion reactions with guanosine
Arylnitrenium ions have gained attention for their high reactivity toward guanosine, which in
some cases has been linked to carcinogenesis. Although many studies have examined …
some cases has been linked to carcinogenesis. Although many studies have examined …
Time-resolved spectroscopic and density functional theory investigation of the influence of the leaving group on the generation of a binol quinone methide
Quinone methides are important reactive intermediates in photobiology and photochemistry,
with little known regarding the photo-induces generation of reactive quinone methides …
with little known regarding the photo-induces generation of reactive quinone methides …
Mechanistic Studies on the Decomposition of Photoactive Nitrosyl Hydride (HNO) Precursors
R Cink - 2019 - openrepository.aut.ac.nz
Nitroxyl hydride (HNO) is a biologically relevant, highly reactive molecule and is a redox
cousin of NO. HNO shows extremely promising pharmacological properties, including …
cousin of NO. HNO shows extremely promising pharmacological properties, including …
Time-resolved spectroscopic and density functional theory investigation of the photogeneration of a bifunctional quinone methide in neutral and basic aqueous …
Binol quinone methides (BQMs) can be generated from 1, 1′-(2, 2′-dihydroxy-1, 1′-
binaphthyl-6, 6′-diyl) bis (N, N, N-trimethylmethanamiuium) bromide (BQMP-b) in a 1: 1 …
binaphthyl-6, 6′-diyl) bis (N, N, N-trimethylmethanamiuium) bromide (BQMP-b) in a 1: 1 …