Transition-metal complexes are attractive targets for the design of catalysts and functional
materials. The behavior of the metal–organic bond, while very tunable for achieving target …

A highly robust metal–organic framework (MOF) constructed from Zr6 oxo clusters and Fe
(III) porphyrin linkers, PCN-223-Fe was investigated as a heterogeneous catalyst for oxygen …

Iron (III) meso-tetra (2-carboxyphenyl) porphine chloride (1) was investigated as a soluble
electrocatalyst for the oxygen reduction reaction (ORR) in acetonitrile with [H (DMF)+] OTf …

Halogenation of an iron porphyrin causes severe saddling of the macrocyclic structure and a
large positive shift in the iron (III)/(II) redox couple. Although perhalogenated iron (II) …

Abstract The germanium (iv), tin (iv), and phosphorus (v) complexes of tris
(pentafluorophenyl) corrole were prepared and investigated by electrochemistry for …

The log k cat values for the dismutation of O2•-by a series of monohydroxoiron (III) and
aquamanganese (III) porphyrins, including ortho, meta, and para isomers of 5, 10, 15, 20 …

For a future hydrogen economy, non‐precious metal catalysts for the water splitting
reactions are needed that can be implemented on a global scale. Metal‐nitrogen‐carbon …

The development of artificial molecular catalysts for CO2 reduction is the key to solving
energy and environmental problems. Although chemical modifications can generally …

Controlled switching of the spin state of transition metal ions, particularly of FeII and FeIII, is
a prerequisite to achieve selectivity, efficiency, and catalysis in a number of metalloenzymes …

Iron and manganese hemes are" high-valent" when the valence state of the metal exceeds
III. Redox chemistry of the high valent metal complexes involves redistribution of holes and …