Reactivity of metal dioxo complexes

CA Canote, SM Kilyanek - Dalton Transactions, 2024 - pubs.rsc.org
Metal dioxo chemistry and its diverse reactivity are presented with an emphasis on the
mechanisms of reactivity. Work from approximately the last decade is surveyed and …

Influence of coordination geometry on the ring opening of benzoxazine: Oxidovanadium (V), dioxidomolybdenum (VI) and dioxidotungsten (VI) complexes of …

MR Maurya, N Kumar, SK Maurya… - European Journal of …, 2023 - Wiley Online Library
Mono benzoxazine appended N‐capped amino bis (disubstitutedphenol) ligands [II (a–c)]
upon reaction with VVO (OEt) 3 in a 1: 1 molar ratio in EtOH/MeOH give [{VVO} en (3, 5 …

Synthesis, characterization and biomimetic activity of heterogenized dioxidomolybdenum (VI) complex and its homogeneous analogue

MR Maurya, A Chauhan - Topics in Catalysis, 2023 - Springer
Abstract Cis-[MoVIO2 (CH3-hptb)(MeOH)](1) has been synthesized by the reaction of
[MoVIO2 (acac) 2] and deferasirox [ICL670: 4-[3, 5-bis (2-hydroxyphenyl)-1H-1, 2, 4-triazol-1 …

Vanadium (v) and molybdenum (vi) complexes containing ono tridentate schiff bases and their application as catalysts for oxidative bromination of phenols

MR Maurya, N Jangra, F Avecilla, N Ribeiro… - …, 2019 - Wiley Online Library
Abstract Condensation of 2, 4‐dihydroxyacetophenone with isonicotinoyl hydrazide and
nicotinoyl hydrazide in an equimolar ratio in methanol results in the formation of two stable …

New bis [MoO2] and [MoO (O2)] compounds: An artificial enzyme with peroxidase activity against o-phenylenediamine and dopamine

L Rana, G Hundal - Journal of Inorganic Biochemistry, 2023 - Elsevier
In this study, two binuclear dioxido-and oxidoperoxido molybdenum (VI) complexes,[{Mo VI
O 2} 2 (L)(H 2 O) 2] 1 and [{Mo VI O (O 2)} 2 (L)(H 2 O) 2] 2, were synthesized. Complex 1 …

Catalytic activity of a new dioxidomolybdenum (vi) complex with a bipodal N 2 O-donor ligand in sulfur compound oxidation

PMA Machado, JM Barreto, RS Motta… - New Journal of …, 2023 - pubs.rsc.org
A new dinuclear dioxidomolybdenum (VI) complex [(MoO2) 2 (BPA) 2 (μ-O)] was
synthesized by the reaction between the tridentate N2O-donor ligand N-(2-hydroxybenzyl)-N …

New bis [cis-{MoO 2}] complexes with dihydrazone ligands: synthesis, characterization, theoretical investigation and their peroxidase mimicking activity

L Rana, G Hundal - Dalton Transactions, 2023 - pubs.rsc.org
Three binuclear dioxidomolybdenum complexes designated as [{MoVIO2} 2 (L1)(H2O) 2]
1,[{MoVIO2} 2 (L2)(H2O) 2] 2, and [{MoVIO2} 2 (L3)(H2O) 2] 3 with dihydrazone ligands …

Biomimetic Oxidative Bromination by cis‐Dioxidotungsten(VI) Complexes of Salan Type N,N'‐Capped Linear Tetradentate Amino Bisphenol

MR Maurya, SK Maurya, N Kumar… - European Journal of …, 2021 - Wiley Online Library
Abstract Reaction of [WVIO2 (acac) 2](Hacac= acetylacetone) with salan‐type dibasic
tetradentate ONNO donor Mannich bases derived from ethylenediamine, formaldehyde and …

Synthesis, characterization and catalytic activity of dioxidouranium (VI) complexes of ONNO tetradentate Mannich bases

MR Maurya, B Mengesha, SK Maurya, F Avecilla - Inorganica Chimica Acta, 2019 - Elsevier
The reaction of dibasic tetradentate ONNO donor Mannich bases, derived from
ethylenediamine and 2, 4–di–tert–butylphenol (H 2 L 1)(I), 2, 4–di–methylphenol (H 2 L …

Styrene selective oxidation to benzaldehyde catalyzed by acylhydrazone Mo complexes: Reaction parameter effects and kinetics

S Yang, G Li, Y Yang, M Zhu, Y Fu, N Xing, L Shi - Inorganica Chimica Acta, 2022 - Elsevier
Three acylhydrazone molybdenum complexes were synthesized for the first time:[MoO 2 L 1
(EtOH)](1),[MoO 2 L 2 (EtOH)](2),[MoO 2 L 3 (EtOH)](3),[H 2 L 1= 4-bromo-N'-(3, 5-dichloro-2 …