Reactivity of metal dioxo complexes
CA Canote, SM Kilyanek - Dalton Transactions, 2024 - pubs.rsc.org
Metal dioxo chemistry and its diverse reactivity are presented with an emphasis on the
mechanisms of reactivity. Work from approximately the last decade is surveyed and …
mechanisms of reactivity. Work from approximately the last decade is surveyed and …
Influence of coordination geometry on the ring opening of benzoxazine: Oxidovanadium (V), dioxidomolybdenum (VI) and dioxidotungsten (VI) complexes of …
Mono benzoxazine appended N‐capped amino bis (disubstitutedphenol) ligands [II (a–c)]
upon reaction with VVO (OEt) 3 in a 1: 1 molar ratio in EtOH/MeOH give [{VVO} en (3, 5 …
upon reaction with VVO (OEt) 3 in a 1: 1 molar ratio in EtOH/MeOH give [{VVO} en (3, 5 …
Synthesis, characterization and biomimetic activity of heterogenized dioxidomolybdenum (VI) complex and its homogeneous analogue
Abstract Cis-[MoVIO2 (CH3-hptb)(MeOH)](1) has been synthesized by the reaction of
[MoVIO2 (acac) 2] and deferasirox [ICL670: 4-[3, 5-bis (2-hydroxyphenyl)-1H-1, 2, 4-triazol-1 …
[MoVIO2 (acac) 2] and deferasirox [ICL670: 4-[3, 5-bis (2-hydroxyphenyl)-1H-1, 2, 4-triazol-1 …
Vanadium (v) and molybdenum (vi) complexes containing ono tridentate schiff bases and their application as catalysts for oxidative bromination of phenols
Abstract Condensation of 2, 4‐dihydroxyacetophenone with isonicotinoyl hydrazide and
nicotinoyl hydrazide in an equimolar ratio in methanol results in the formation of two stable …
nicotinoyl hydrazide in an equimolar ratio in methanol results in the formation of two stable …
New bis [MoO2] and [MoO (O2)] compounds: An artificial enzyme with peroxidase activity against o-phenylenediamine and dopamine
In this study, two binuclear dioxido-and oxidoperoxido molybdenum (VI) complexes,[{Mo VI
O 2} 2 (L)(H 2 O) 2] 1 and [{Mo VI O (O 2)} 2 (L)(H 2 O) 2] 2, were synthesized. Complex 1 …
O 2} 2 (L)(H 2 O) 2] 1 and [{Mo VI O (O 2)} 2 (L)(H 2 O) 2] 2, were synthesized. Complex 1 …
Catalytic activity of a new dioxidomolybdenum (vi) complex with a bipodal N 2 O-donor ligand in sulfur compound oxidation
PMA Machado, JM Barreto, RS Motta… - New Journal of …, 2023 - pubs.rsc.org
A new dinuclear dioxidomolybdenum (VI) complex [(MoO2) 2 (BPA) 2 (μ-O)] was
synthesized by the reaction between the tridentate N2O-donor ligand N-(2-hydroxybenzyl)-N …
synthesized by the reaction between the tridentate N2O-donor ligand N-(2-hydroxybenzyl)-N …
New bis [cis-{MoO 2}] complexes with dihydrazone ligands: synthesis, characterization, theoretical investigation and their peroxidase mimicking activity
Three binuclear dioxidomolybdenum complexes designated as [{MoVIO2} 2 (L1)(H2O) 2]
1,[{MoVIO2} 2 (L2)(H2O) 2] 2, and [{MoVIO2} 2 (L3)(H2O) 2] 3 with dihydrazone ligands …
1,[{MoVIO2} 2 (L2)(H2O) 2] 2, and [{MoVIO2} 2 (L3)(H2O) 2] 3 with dihydrazone ligands …
Biomimetic Oxidative Bromination by cis‐Dioxidotungsten(VI) Complexes of Salan Type N,N'‐Capped Linear Tetradentate Amino Bisphenol
Abstract Reaction of [WVIO2 (acac) 2](Hacac= acetylacetone) with salan‐type dibasic
tetradentate ONNO donor Mannich bases derived from ethylenediamine, formaldehyde and …
tetradentate ONNO donor Mannich bases derived from ethylenediamine, formaldehyde and …
Synthesis, characterization and catalytic activity of dioxidouranium (VI) complexes of ONNO tetradentate Mannich bases
The reaction of dibasic tetradentate ONNO donor Mannich bases, derived from
ethylenediamine and 2, 4–di–tert–butylphenol (H 2 L 1)(I), 2, 4–di–methylphenol (H 2 L …
ethylenediamine and 2, 4–di–tert–butylphenol (H 2 L 1)(I), 2, 4–di–methylphenol (H 2 L …
Styrene selective oxidation to benzaldehyde catalyzed by acylhydrazone Mo complexes: Reaction parameter effects and kinetics
S Yang, G Li, Y Yang, M Zhu, Y Fu, N Xing, L Shi - Inorganica Chimica Acta, 2022 - Elsevier
Three acylhydrazone molybdenum complexes were synthesized for the first time:[MoO 2 L 1
(EtOH)](1),[MoO 2 L 2 (EtOH)](2),[MoO 2 L 3 (EtOH)](3),[H 2 L 1= 4-bromo-N'-(3, 5-dichloro-2 …
(EtOH)](1),[MoO 2 L 2 (EtOH)](2),[MoO 2 L 3 (EtOH)](3),[H 2 L 1= 4-bromo-N'-(3, 5-dichloro-2 …