The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …

A sulfonamide is a functional group that is the basis of several sulfa drugs and thereby are
very much important scaffolds in medicinal as well as in synthetic organic chemistry …

Sulfur (VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages;
however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the …

Simple access to aryl sulfinates from aryl iodides and bromides is reported using an
inexpensive Ni‐electrocatalytic protocol. The reaction exhibits a broad scope, uses stock …

The past decade has witnessed remarkable growth of catalytic transformations in organic
sulfur (VI) fluoride chemistry. This Perspective concentrates exclusively on foundational …

Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …

Sulfonyl fluorides are key components in the fields of chemical biology, materials science
and drug discovery. In this line, the highly active SO2F radical has been employed for the …

Sulfonyl compounds have attracted considerable interest due to their extensive applications
in drug discovery. Access to the assembly of SO2-containing compounds via the …

A Bi-catalyzed synthesis of sulfonyl fluorides from the corresponding (hetero) aryl boronic
acids is presented. We demonstrate that the organobismuth (III) catalysts bearing a bis-aryl …

A practical electrochemically driven method for fluorosulfonylation of both aryl and alkyl
thianthrenium salts has been disclosed. The strategy does not need external redox reagents …