Dimerization of Conjugated Radical Cations: An Emerging Non‐Covalent Interaction for Self‐Assembly

DW Zhang, J Tian, L Chen, L Zhang… - Chemistry–An Asian …, 2015 - Wiley Online Library
Aromatic stacking has played a significant role in the design of discrete supramolecular
systems. However, for many years, the stacking of conjugated radical cations has been …

50th Anniversary Perspective: Conducting/Semiconducting Conjugated Polymers. A Personal Perspective on the Past and the Future

TM Swager - Macromolecules, 2017 - ACS Publications
It has been about 40 years since the field of organic conducting polymers was ignited by the
demonstration of metallic conductivity in polyacetylene. A retrospective view of this research …

Highly stable tetrathiafulvalene radical dimers in [3] catenanes

JM Spruell, A Coskun, DC Friedman, RS Forgan… - Nature …, 2010 - nature.com
Abstract Two [3] catenane 'molecular flasks' have been designed to create stabilized, redox-
controlled tetrathiafulvalene (TTF) dimers, enabling their spectrophotometric and structural …

Charge‐transfer character in a covalent diketopyrrolopyrrole dimer: implications for singlet fission

CM Mauck, YJ Bae, M Chen, N Powers‐Riggs… - …, 2018 - Wiley Online Library
Diketopyrrolopyrrole (DPP) is a strongly absorbing, photostable chromophore that can
undergo singlet fission (SF), a photophysical process that promises to significantly enhance …

Interchromophoric interactions in chiral X-type π-conjugated oligomers: a linear and nonlinear optical study

D Cornelis, E Franz, I Asselberghs… - Journal of the …, 2011 - ACS Publications
A concept of chiral, X-type organized π-conjugated oligomers, linked by means of a
binaphthalene pincer, is presented. NMR spectroscopy and cyclic and differential pulse …

Photophysical and theoretical investigations of the [8] cycloparaphenylene radical cation and its charge-resonance dimer

MR Golder, BM Wong, R Jasti - Chemical Science, 2013 - pubs.rsc.org
Treatment of [8] cycloparaphenylene (CPP) with the oxidant triethyloxonium
hexachloroantimonate afforded an isolable radical cation of the parent carbon nanohoop …

Validation of density functionals for pancake-bonded π-dimers; dispersion is not enough

Z Mou, YH Tian, M Kertesz - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
π-Stacking pancake bonding between radicals poses special challenges to density
functional theories (DFTs) due to their shorter than van der Waals contact distances, their …

Stepwise construction of head-to-tail-type oligothiophenes via iterative palladium-catalyzed CH arylation and halogen exchange

N Masuda, S Tanba, A Sugie, D Monguchi… - Organic …, 2009 - ACS Publications
Stepwise Construction of Head-to-Tail-Type Oligothiophenes via Iterative Palladium-Catalyzed
CH Arylation and Halogen Exchange | Organic Letters ACS ACS Publications C&EN CAS …

Electrochemical generation and spectroscopic characterization of charge carriers within isolated planar polythiophene

R Shomura, K Sugiyasu, T Yasuda, A Sato… - …, 2012 - ACS Publications
In order to unveil the nature of charge carriers in a doped polythiophene, a sterically isolated
polythiophenene, poly (1EDOT), was electrochemically synthesized on electrodes …

Towards highly conducting bicarbazole redox polymer films with plateau-like conductivities

C Malacrida, Y Lu, K Dirnberger… - Journal of Materials …, 2020 - pubs.rsc.org
Chemical doping of redox polymer films based on triphenylamine (PVTPA), phenylcarbazole
(PVPhCbz) and carbazole (PVCbz) pendant redox units is performed with different …