The methyl iodide A-band photodissociation process CH3Ih→ CH3 (v, N, K) I (2P3/2),
I*(2P1/2) has been studied in a cold molecular beam. Full three-dimensional state-specific …

This review summarizes the recent combined experimental and theoretical effort of high-
resolution spectroscopy, mass spectrometry and quantum chemical calculations to …

Advances in the time propagation of multidimensional wave packets are exploited to present
the A‐band photodissociation dynamics of methyl iodide for five active vibrational modes on …

As highly reactive intermediates, radicals are responsible for a vast array of fundamental gas
and condensed phase processes ranging from atmospheric chemistry1 to combustion2, 3 to …

Threshold photoelectron spectra (TPES) of the isotopomers of the methyl radical (CH3,
CH2D, CHD2, and CD3) have been recorded in the 9.5− 10.5 eV VUV photon energy range …

ABSTRACT Observations with the Short Wavelength Spectrometer on board the Infrared
Space Observatory have led to the first detection of the methyl radical CH 3 in the interstellar …

Nitromethane (NM), a high explosive (HE) with low sensitivity, is known to undergo
photolysis upon ultraviolet (UV) irradiation. The optical transparency, homogeneity, and …

The thermophysical properties (isobaric heat capacity, entropy, enthalpy increment) of two
prominent radicals, methyl, CH3, and methylene, CH2, were computed using the Nonrigid …

By analysing the properties of the electron density in the structurally simple perhalogenated
ethanes, X3C–CY3 (X, Y= F, Cl), a previously overlooked non-covalent attraction between …

Rate coefficients for the CH3+ CH3 reaction, over the temperature range 300–900 K, have
been corrected for errors in the absorption coefficients used in the original publication …