High-nuclearity silver (I) chalcogenide clusters: A novel class of supramolecular assembly

YP Xie, JL Jin, GX Duan, X Lu, TCW Mak - Coordination chemistry reviews, 2017 - Elsevier
The high-nuclearity silver (I) clusters, a novel class of supramolecular assembly of silver (I)
complexes, were usually prepared by incorporating silver ions with various ligands. Notably …

Ligand-functionalized and ligand-bridged or organyl-separated chalcogenido metalate-based clusters

Z Wu, M Tallu, G Stuhrmann, S Dehnen - Coordination Chemistry Reviews, 2023 - Elsevier
Chalcogenido metalate-based clusters, comprising cluster cores with directly bonded metal
cations and chalcogenide anions, have been a focus of inorganic and materials research for …

Atomically Precise Silver Clusters Stabilized by Lacunary Polyoxometalates with Photocatalytic CO2 Reduction Activity

Y Feng, F Fu, L Zeng, M Zhao, X Xin… - Angewandte Chemie …, 2024 - Wiley Online Library
The syntheses of atomically precise silver (Ag) clusters stabilized by multidentate lacunary
polyoxometalate (POM) ligands have been emerging as a promising but challenging …

Atomically precise site-specific tailoring and directional assembly of superatomic silver nanoclusters

ZY Wang, MQ Wang, YL Li, P Luo, TT Jia… - Journal of the …, 2018 - ACS Publications
Convenient generation of stable superatomic silver clusters and their systematic site-specific
tailoring and directional assembly present an enduring and significant challenge. In this …

Atom-precise modification of silver (I) thiolate cluster by shell ligand substitution: a new approach to generation of cluster functionality and chirality

S Li, XS Du, B Li, JY Wang, GP Li… - Journal of the …, 2018 - ACS Publications
To realize the molecular design of new functional silver (I) clusters, a new synthetic
approach has been proposed, by which the weakly coordinating ligands NO3–in a Ag20 …

Tandem silver cluster isomerism and mixed linkers to modulate the photoluminescence of cluster‐assembled materials

RW Huang, XY Dong, BJ Yan, XS Du… - Angewandte Chemie …, 2018 - Wiley Online Library
Silver chalcogenolate cluster assembled materials (SCAMs) are a category of promising
light‐emitting materials the luminescence of which can be modulated by variation of their …

Anisotropic Assembly of Ag52 and Ag76 Nanoclusters

JW Liu, L Feng, HF Su, Z Wang, QQ Zhao… - Journal of the …, 2018 - ACS Publications
Although there has been an upsurge of interest in anisotropic assembly of inorganic
nanoparticles, atomically precise self-assembly of anisotropic metal clusters is extremely …

Luminescent Molecular Ag−S Nanocluster [Ag62S13(SBut)32](BF4)4

G Li, Z Lei, QM Wang - Journal of the American Chemical Society, 2010 - ACS Publications
The first observation of luminescence from a structurally well-defined Ag2S molecular
nanocluster is reported. Reaction of AgSBu t/AgBF4 with N2H4 in methanol affords the …

Guest‐Triggered Aggregation‐Induced Emission in Silver Chalcogenolate Cluster Metal–Organic Frameworks

XH Wu, P Luo, Z Wei, YY Li, RW Huang… - Advanced …, 2019 - Wiley Online Library
Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be
an effective strategy for constructing metal–organic frameworks (MOFs) with intense …

Facile Aqueous‐Phase Synthesis of Biocompatible and Fluorescent Ag2S Nanoclusters for Bioimaging: Tunable Photoluminescence from Red to Near Infrared

C Wang, Y Wang, L Xu, D Zhang, M Liu, X Li, H Sun… - Small, 2012 - Wiley Online Library
Low toxicity and fluorescent nanomaterials have many advantages in biological imaging.
Herein, a novel and facile aqueous‐phase approach to prepare biocompatible and …